Capillary Zone Electrophoresis of Iridium(III) and Ruthenium(II) Polypyridyl Complexes in Non-Aqueous Solvents

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Publisher： Taylor & Francis Ltd

ISSN： 0003-2719

Source： Analytical Letters, Vol.40, Iss.9, 2007-06, pp. : 1791-1799

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Abstract

A method of non-aqueous capillary zone electrophoresis has been optimised for the characterisation of five functionalised mixed-ligand iridium(III) polypyridyl complexes and four functionalised ruthenium(II) bis-terpyridine complexes. Their mobilities, the relation to their molar mass and the capillary lifetime (measured in number of injections) have been determined.

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