Synthesis and Characterization of NiO/Mesoporous Silica Nanocomposite

Author： Niu Kui Dong Weifu Chen Mingqing Ni Zhongbin

ISSN： 1058-4587

Source： Integrated Ferroelectrics, Vol.128, Iss.1, 2011-01, pp. : 135-141

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Abstract

NiO/mesoporous silica nanocomposite was synthesized through anionic-surfactant-templated route by using N-hexadecyl ethylenediamine triacetate (HED3A) as structure directing agent. A temperature of 600°C was chosen to remove the template after an initial thermogravimetric (TG) analysis. Based on the metal sequestration of the template, Ni²⁺ was introduced into silica matrix and NiO was finally embedded into mesopores after calcination. The composition of NiO/mesoporous silica composite was qualitatively characterized and quantitatively expressed by Fourier transform infrared (FTIR) spectroscopy, X-ray powder diffraction (XRD) pattern and Energy-dispersive X-ray (EDX) spectroscopy. The composite with high nickel content has a BET surface area reached 676 m²g⁻¹ and a pore diameter centered at 3-4 nm. Small-angle X-ray diffraction (SAXRD) pattern indicates that the material possesses ordered two-dimensional (2-D) p6mm hexagonal mesostructure. High resolution transmission electron microscopy (HRTEM) investigation on the structural characteristics confirms the mesostructure and shows that NiO clusters with a uniform size of 15 nm are encapsulated in mesoporous silica.