Author： Maruani J. Coope J.A.R. McDowell C.A.
Publisher： Taylor & Francis Ltd
ISSN： 1362-3028
Source： Molecular Physics, Vol.18, Iss.2, 1970-02, pp. : 165-176
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
A more detailed analysis is given here of the singularities in the E.S.R. spectrum of the trifluoromethyl radical in a polycrystalline matrix. Some of the unexplained ‘extra' lines are interpreted as resulting from orientations such that some of the resonance fields are stationary as a result of ‘non-crossing' of the manifolds of resonance fields due to second-order splitting. A calculation of the polycrystalline spectrum for a planar axial model of · CF 3 is presented, and shows that the second-order effect is of the right order of magnitude.
Related content
The E.S.R. spectrum of the tropolonyl radical
By Dixon William Foster Wendy Murphy D.
Molecular Physics, Vol. 27, Iss. 6, 1974-06 ,pp. :
Access to resources
Recommend
Electron collisions with the CF3 radical using the R-matrix method
New Journal of Physics, Vol. 5, Iss. 1, 2003-11 ,pp. :
Access to resources