Publisher: Taylor & Francis Ltd
ISSN: 1362-3028
Source: Molecular Physics, Vol.81, Iss.1, 1994-01, pp. : 69-85
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
High-resolution polarized and depolarized continuum resonance Raman spectra of isotopically pure 127 I 35 Cl for fundamental and overtone transitions Δ&ngr; = 1-4 with excitation from the green to the blue spectral region have been used to determine the repulsive part of the potential function 3 &Pgr; 0+ as well as the pure repulsive potential function 1 &Pgr; 1 . The latter is responsible for the predissociation of the 3 &Pgr; 0+ state. The continuum resonance Raman spectra are highly sensitive to the position and shape of the excited state potential functions and hence allow an accurate determination of these functions. The experimental spectra were simulated applying time dependent as well as time independent second-order perturbation theory.
Related content
Continuum resonance Raman scattering in 127 I 79 Br
By Vogt P. Schmitt M. Kiefer W.
Vibrational Spectroscopy, Vol. 12, Iss. 2, 1996-10 ,pp. :
The a 3 Pi- X 1 Sigma + Transitions of 69 Ga 35 Cl and 71 Ga 127 I
Journal of Molecular Spectroscopy, Vol. 179, Iss. 2, 1996-10 ,pp. :
Theoretical study of Raman scattering from pure liquids
Molecular Physics, Vol. 42, Iss. 2, 1981-02 ,pp. :