Indole Alkaloids :An Introduction to the Enamine Chemistry of Natural Products

Publication subTitle :An Introduction to the Enamine Chemistry of Natural Products

Author: Taylor   W. I.;Robinson   Robert  

Publisher: Elsevier Science‎

Publication year: 2013

E-ISBN: 9781483221748

P-ISBN(Paperback): 9781483196718

P-ISBN(Hardback):  9781483196718

Subject: O62 Organic Chemistry

Language: ENG

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Description

A Course in Organic Chemistry Advanced Section, Volume 27: Indole Alkaloids: An Introduction to the Enamine Chemistry of Natural Products describes the chemistry of selected alkaloids that contain indolic or closely related nuclei. Some five hundred of these compounds have been obtained from about three hundred plants mostly of the family Apocynaceae.
This book is composed of 12 chapters that specifically cover the chemistry of the complex indoles. The introductory chapters deal with the origin, isolation, characterization, basic chemistry, and simple derivatives of indole alkaloids. The remaining chapters examine the biogenesis, basic chemistry, stereochemistry, and structure of selected complex alkaloids of various origins. These chapters include tetrahydro-?-carboline, strychnos, iboga, picralima, and eburnamine alkaloids, cinchonamine, quinamine, and ajmaline-sarpagine bases.
This text is of great value to organic chemists and researchers.

Chapter

CHARTS

PREFACE

INTRODUCTION

CHAPTER I. SOLATION AND CHARACTERIZATION OF INDOLE ALKALOIDS

GENERAL REFERENCES

CHAPTER II. THE ORIGIN OF INDOLE ALKALOIDS

SUGGESTED READING

CHAPTER III. BASIC CHEMICAL CONSIDERATIONS

CHAPTER IV. SIMPLE DERIVATIVES OF TRYPTOPHAN

The Tryptamines

Physostigmine

The Harmala Bases

Rutaecarpine

Calycanthine

The Ergolines

SUGGESTED READING

CHAPTER V. THE COMPLEX TETRAHYDRO-β-CARBOLINE ALKALOIDS

The Yohimbanes

The Yohimbines

C-3 Stereochemistry

The seco Compounds

Burnamicine

Ring Ε Oxygen Heterocycles

SUGGESTED READING

CHAPTER VI. THE STRYCHNOS ALKALOIDS

STRYCHNINE

AKUAMMICINE

SUGGESTED READING

CHAPTER VII. CINCHONAMINE AND QUINAMINE

Cinchonamine

Quinamine

SUGGESTED READING

CHAPTER VIII. THE AJMALINE-SARPAGINE BASES

Ajmaline

Sarpagine

Vobasine

Voachalotine

SUGGESTED READING

CHAPTER IX. THE IBOGA ALKALOIDS

Ibogaine

Voacangine

Catharanthine and Cleayamine

CHAPTER Χ. THE EBURNAMINE ALKALOIDS

Canthin-6-ones

Eburnamonine

Eburnamine

Vincamine

Schizozygine

SUGGESTED READING

CHAPTER XI. ASPIDOSPERMA BASES

Aspidospermine

The Mass Spectrum of Aspidospermine

Kopsine

SUGGESTED READING

CHAPTER XII. PICRALIMA ALKALOIDS

Picraline

EPILOGUE

INDEX OF PLANT NAMES

INDEX OF CHEMICALCOMPOUNDS, ETC.

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