Publisher： John Wiley & Sons Inc
ISSN： 1615-4150
Source： ADVANCED SYNTHESIS & CATALYSIS, Vol.357, Iss.5, 2015-03, pp. : 933-939
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Abstract
We describe here an efficient and regioselective synthesis of arylselanyl anilines by copper‐catalyzed direct arylselenation of arylamines. Using a catalytic amount of copper iodide in dimethyl sulfoxide at 110 °C under an air atmosphere, a range of arylselanyl anilines was obtained directly from substituted diaryl diselenides in moderate to good yields via CH bond cleavage of aryl amines.
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