Synthesis and Structural Characterization of [(Pb6I22)(DMF)2(DPB)5] Directed by 1,1′-dipentyl-4,4′-bipyridinium Cation

Author： Zhang Wenli   Zhang Ning   Shen Lixia   Wu Huanhuan   Li Xinghui   Li Si   Yue Junming   Niu Yunyin  

Publisher： Taylor & Francis Ltd

E-ISSN： 1553-3182|45|9|1347-1351

ISSN： 1553-3174

Source： Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol.45, Iss.9, 2015-09, pp. : 1347-1351

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Abstract

In this study, one novel hexanuclear black crystals, namely [(Pb6I22)(DMF)2(DPB)5] were obtained from the solution-phase reaction of PbI2 in the present of excess KI directed by viologen-based linear templates in MeOH/DMF (DPB= 1,1′-dipentyl-4,4′-bipyridinium). Single-crystal X-ray diffraction analysis showed that this supramolecular compound crystallized in the monoclinic system with the space group P2(1)/c. Electrostatic interactions between the organic dications and inorganic moieties and hydrogen-bond interactions between structural unit are present and contribute to the crystal packing. IR spectroscopy was performed to further characterize title compound.

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