Publisher： Bentham Science Publishers
E-ISSN： 1875-6271|9|1|96-113
ISSN： 1570-1794
Source： Current Organic Synthesis, Vol.9, Iss.1, 2012-02, pp. : 96-113
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Abstract
This Review reports recent developments in the synthesis of benzo-fused heterocycles through Pd-catalyzed carbon-carbon and carbon-heteroatom bond forming reactions via direct C-H activation. Nitrogen-, oxygen- and sulfur-containing heterocyclic rings can be rapidly assembled starting from precursors with minimal preactivation. Compared to classical coupling reactions (i.e. Suzuki, Stille, Buchwald-Hartwig), these methods provide a more straightforward and economical route to various heterocyclic scaffolds, which is of practical importance considering their role in biology and pharmaceutical industry.
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