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Solvent‐Induced Facile Synthesis of Cubic‐, Spherical‐, and Honeycomb‐Shape Palladium N‐Heterocyclic Carbene Particles and Catalytic Applications in Cyanosilylation

Publisher: John Wiley & Sons Inc

E-ISSN: 1613-6829|11|30|3642-3647

ISSN: 1613-6810

Source: SMALL, Vol.11, Iss.30, 2015-08, pp. : 3642-3647

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Abstract

The facile synthesis of palladium N‐heterocyclic carbene (NHC) particles with spherical, cubic, and honeycomb morphologies is accomplished. The structures of cubic and honeycomb particles are defined as an unprecedented trinuclear palladium–NHC complex. An obvious effect of particle morphologies on catalytic activity and recyclability is observed in hetero­geneous cyanosilylation.

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