Publisher: John Wiley & Sons Inc
E-ISSN: 2192-6549|9-4536|9|786-792
ISSN: 0009-4536
Source: JOURNAL OF THE CHINESE CHEMICAL SOCIETY (ELECTRONIC), Vol.9-4536, Iss.9, 2015-09, pp. : 786-792
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
AbstractThree new complexes {[Cu(L1)2(NO3)2]⋅H2O}oo (1), {[Cu4(L2)2(OAc)8]‐CH3CH2OH}oo (2) and [Cd2(L3)3(NO3)4(H2O)2]oo (3) (L1=4‐phenyl‐7‐(pyridine‐3‐yl)‐1,2,4‐triazolo[3,4‐b]‐1,3,4‐thiadiazole, L2=4‐(pyridine‐3‐yl)‐7‐phenyl‐1,2,4‐triazolo[3,4‐b]‐1,3,4‐thiadiazole, and L3=4‐(pyridine‐4‐yl)‐7‐phenyl‐1,2,4‐triazolo[3,4‐b]‐1,3,4‐thiadiazole) have been synthesized and characterized by elemental analyses, IR spectra and single crystal X‐ray diffraction. The structural analyses reveal that complex 1 is a neutral 2‐D network structure with a 44 topology, 2 has a 1‐D neutral coordination chain with a [Cu2(CH3COO)4] dinuclear structural unit bridged by four acetate ions, and 3 is a neutral rhombohedral grid structure. All thecomplexes are air stable at room temperature. Furthermore, the fluorescent properties of complex 3 and corresponding ligand L3 have been investigated and discussed.
Related content
JOURNAL OF THE CHINESE CHEMICAL SOCIETY (ELECTRONIC), Vol. 62, Iss. 9, 2015-09 ,pp. :
ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol. 640, Iss. 11, 2014-09 ,pp. :