Publisher： John Wiley & Sons Inc
E-ISSN： 1867-3899|7|7|1177-1183
ISSN： 1867-3880
Source： CHEMCATCHEM (ELECTRONIC), Vol.7, Iss.7, 2015-04, pp. : 1177-1183
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Abstract
AbstractThe first methodology for the direct reductive deoxygenation of ketones catalyzed by high‐valent oxo‐rhenium complexes by using a silane as reducing agent is described. The systems PhSiH3/[ReOCl3(SMe2)(OPPh3)] (2 mmol/5 mol %) and PhSiH3/[ReOCl3(PPh3)2] (2 mmol/5 mol %) proved to be efficient for the deoxygenation of aryl ketones, producing selectively the corresponding alkane, or a mixture of alkane and alkene derivatives with the alkane as the major product.
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