Microplastic Pollutants

Author: Crawford   Christopher Blair;Quinn   Brian  

Publisher: Elsevier Science‎

Publication year: 2016

E-ISBN: 9780128104699

P-ISBN(Paperback): 9780128094068

Subject: X5 Environmental Pollution and Prevention

Keyword: 环境科学、安全科学

Language: ENG

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Description

Microplastic Pollutants introduces the reader to the growing problem of microplastic pollution in the aquatic environment and is the first ever book dedicated exclusively to the subject of microplastics. Importantly, this timely full-colour illustrated multidisciplinary book highlights the very recent realization that microplastics may transport toxic chemicals into food chains around the world.

Microplastic pollutants is currently an important topic in both industry and academia, as well as among legislative bodies, and research in this area is gaining considerable attention from both the worldwide media and scientific community on a rapidly increasing scale.

Ultimately, this book provides an excellent source of reference and information on microplastics for scientists, engineers, students, industry, policy makers and citizens alike.

  • A detailed chronological history of plastic materials from their creation until the present day
  • Extensive review and discussion of the existing literature on the interactions of microplastics with chemical pollutants and their effects on aquatic life
  • Explanation and provision of the techniques used for the detection, separation and identification of microplastics
  • Detailed multidisciplinary information on the way in which plastic materials and microplastics behave in the aquatic environment
  • The provision of extensive multidisciplinary reference data relating to plastic materials a

Chapter

Microplastic Pollutants

Microplastic Pollutants

Copyright

Contents

About the Author, Christopher Blair Crawford

About the Author, Brian Quinn

Foreword

Preface

Acknowledgments

1 - The emergence of plastics

Introduction

What are plastics?

The advent of plastics

The early history of plastics

1862–98

1899–1931

1932–44

2 - The contemporary history of plastics

The modern history of plastics

1945–62

1963–89

1990–present

3 - Plastic production, waste and legislation

Global production of plastics

Long-term forecasts

Plastic waste

What are macroplastics?

Floating macroplastics

Beached macroplastics

Beach cleanups

Submerged macroplastics

Macroplastic litter legislation

International

Regional

National

Plastics recycling

The ASTM International Resin Identification Coding System

Applications of plastics

4 - Physiochemical properties and degradation

The structure of plastics

Polymerisation

Chain-growth (addition polymers)

Step growth (condensation polymers)

Stereochemistry

Crystallinity

Branching

Copolymers

Polymer blends

Commodity plastics

Polyethylene terephthalate (PET)

Polyethylene (PE)

Polyvinyl chloride (PVC)

Polypropylene (PP)

Polystyrene (PS)

Polycarbonate (PC)

Poly(methyl methacrylate) (PMA) (Fig. 4.20)

Polytetrafluoroethylene (PTFE)

Acrylonitrile butadiene styrene (ABS)

Polyamide (nylon)

Polychloroprene (neoprene)

Degradation

Biotic degradation and biodegradable plastics

Polyhydroxybutyrate (PHB)

Polycaprolactone (PCL)

Polylactic acid (PLA)

Plastic degrading insects

Plastic degrading microorganisms and fungi

Abiotic degradation

Chemical additives

Characteristic weaknesses of common plastics

Thermal degradation

Initiation

Propagation

Termination

Photo-oxidative degradation

Atmospheric oxidation and hydrolytic degradation

Mechanical degradation

Susceptibly of plastics in different marine zones

5 - Microplastics, standardisation and spatial distribution

What are microplastics?

What are plasticles?

The history of microplastics

Primary microplastics

Secondary microplastics

Microplastic litter legislation

Microplastic characteristics

Microplastic density

Microplastics in the terrestrial environment and the atmosphere

Microplastics in lakes

Microplastics in rivers and estuaries

Microplastics in marine surface waters

The mystery of the missing plastic

Microplastics in marine sediments and shorelines

The global abundance of microplastics in marine surface waters and sediments

Weathering of microplastics

6 - The interactions of microplastics and chemical pollutants

Persistent organic pollutants (POPs)

Classes of persistent organic pollutants (POPs)

Chlordane

Dichlorodiphenyltrichloroethane (DDT)

Hexachlorocyclohexane (HCH)

Perfluoroalkylates

Phthalates

Polycyclic aromatic hydrocarbons (PAHs)

Polybrominated diphenyl ethers (PBDEs)

Polychlorinated biphenyls (PCBs)

Microplastics as vectors for chemical pollutants

Desorption

Absorption

Adsorption

The effect of the surface-area-to-volume ratio and weathering

Contaminated microplastics in the aquatic environment

Chlordane contaminated microplastics

Dichlorodiphenyltrichloroethane (DDT) contaminated microplastics

Hexachlorocyclohexane (HCH) contaminated microplastics

Perfluoroalkylate contaminated microplastics

Phthalate contaminated microplastics

PAH contaminated microplastics

Polybrominated diphenyl ether (PBDE) contaminated microplastics

Polychlorinated biphenyl (PCB) contaminated microplastics

Metal and metalloid contaminated microplastics

The effect of salinity

7 - The biological impacts and effects of contaminated microplastics

Ingestion of contaminated microplastics

Aquatic invertebrates

Humans

Seabirds

Marine turtles

Seals and sea otters

Whales

Fish

The effect of colour on the consumption of microplastics

Translocation and trophic transfer of microplastics

Microplastics as vectors for microorganismsand invasive species

8 - Microplastic collection techniques

Collection of microplastics from the environment

Standardisation of collection techniques

Sampling methods

Selective sampling

Volume reduced sampling

Bulk sampling

Environmental parameters

Contamination mitigation

Aquatic sampling

Freshwater

Estuarine

Marine

Surface water sampling

Water column sampling

Horizontal sampling of the water column

Vertical sampling of the water column

Sediment sampling

Intertidal and estuarine

Sub-tidal

9 - Microplastic separation techniques

Separation of microplastics from samples

Visual detection and separation

Water samples

Filtration

Sieving

Sediment samples

Density separation

Elutriation

Froth flotation

Biological samples

Visual detection and separation from biological material

Chemical and enzymatic digestion

10 - Microplastic identification techniques

Identification of microplastics

Sample purification

Visual identification

Selection criteria to identify microplastics

The standardised size and colour sorting (SCS) system for categorising microplastics

The size and colour sorting (SCS) system procedure

Step 1: category

Step 2: type

Step 3: colour

Step 4: polymer

Step 5: quantity

Scanning electron microscope (SEM)

Pyrolysis–gas chromatography–mass spectrometry (Pyr-GC–MS)

Nuclear magnetic resonance (NMR) spectroscopy

Fourier-transform infrared (FTIR) spectroscopy

Fourier-transform infrared (FTIR) spectroscopy reference spectra for plastic materials

Polyethylene terephthalate (Fig. 10.17)

Polyethylene (Fig. 10.18)

Polyvinyl chloride (Fig. 10.19)

Polypropylene (Fig. 10.20)

Polystyrene (Fig. 10.21)

Poly(methyl methacrylate) (Fig. 10.22)

Polytetrafluoroethylene (Fig. 10.23)

Polyamide (nylon) (Fig. 10.24)

Near-infrared (NIR) and short-wavelength infrared (SWIR) spectroscopy

Raman spectroscopy

Raman spectroscopy reference spectra for plastic materials

Polyethylene terephthalate (Fig. 10.28)

Polyethylene (Figs. 10.29 and 10.30)

Polyvinyl chloride (Fig. 10.31)

Polypropylene (Figs. 10.32 and 10.33)

Polystyrene (Fig. 10.34)

Polytetrafluoroethylene (Fig. 10.35)

Polyamide (nylon) (Figs. 10.36 and 10.37)

Future analysis

References

Glossary and list of abbreviations

Index

A

B

C

D

E

F

G

H

I

J

K

L

M

N

O

P

R

S

T

U

V

W

X

Z

Back Cover

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