Catalytic Hydrogenation in Organic Syntheses

Author: Rylander  

Publisher: Elsevier Science‎

Publication year: 2012

E-ISBN: 9780323138536

P-ISBN(Paperback): 9780126053555

P-ISBN(Hardback):  9780126053555

Subject: O621.3 Organic synthesis chemistry.

Language: ENG

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Description

Catalytic Hydrogenation in Organic Syntheses focuses on the process of catalytic hydrogenation in organic synthesis. This book gives the reader easy access to catalytic history, to show what can be done and how to do it. A variety of working generalities and common sense guides are given as aids in selecting catalytic metal, catalyst support, concentration of metal and catalyst, solvent, and reaction conditions. All manner of hydrogenation catalysts are considered and mechanisms of hydrogenation are presented at a level that is useful to the synthetic organic chemist.
This volume is comprised of 15 chapters and begins with an overview of catalytic hydrogenation and heterogeneous hydrogenation catalysts, along with hydrogenation reactors and reaction conditions. The discussion then shifts to the hydrogenation of compounds such as acetylenes, olefins, aldehydes, ketones, nitriles, oximes, acids, esters, lactones, anhydrides, and nitro compounds as well as carbocyclic aromatics and heterocyclic compounds. The reader is also introduced to reductive alkylation, catalytic dehydrohalogenation, and hydrogenolysis of small rings. A chapter on miscellaneous hydrogenolyses concludes the book.
This book will be of interest to organic chemists working in the field of catalytic hydrogenation.

Chapter

Front Cover

pp.:  1 – 4

Copyright Page

pp.:  5 – 6

Table of Contents

pp.:  6 – 10

Preface

pp.:  10 – 12

Chapter 2. Hydrogenation of Acetylenes

pp.:  24 – 42

Chapter 3. Hydrogenation of Olefins

pp.:  42 – 75

Chapter 4. Hydrogenation of Acids, Esters, Lactones, and Anhydrides

pp.:  75 – 83

Chapter 5. Hydrogenation of Aldehydes

pp.:  83 – 93

Chapter 6. Hydrogenation of Ketones

pp.:  93 – 124

Chapter 7. Hydrogenation of Nitro Compounds

pp.:  124 – 149

Chapter 8. Hydrogenation of Nitriles

pp.:  149 – 164

Chapter 9. Hydrogenation of Oximes

pp.:  164 – 176

Chapter 10. Reductive Alkylation

pp.:  176 – 186

Chapter 11. Hydrogenation of Carbocyclic Aromatics

pp.:  186 – 224

Chapter 12. Hydrogenation of Heterocyclic Compounds

pp.:  224 – 246

Chapter 13. Catalytic Dehydrohalogenation

pp.:  246 – 262

Chapter 14. Hydrogenolysis of Small Rings

pp.:  262 – 282

Chapter 15. Miscellaneous Hydrogenolyses

pp.:  282 – 324

Index

pp.:  324 – 337

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