Chapter
Chapter 1: N-Alkyl Amine Synthesis by Catalytic Alcohol Amination
1.2. Homogeneous Catalysts System
1.2.1. Ru Catalyst System
1.2.2. Ir Catalyst System
1.2.3. Pd Catalyst System
1.2.4. Rh/Os/Re/Pt Catalyst Systems
1.2.5. Mo Catalyst System
1.2.6. Co Catalyst System
1.2.7. Cu Catalyst System
1.2.8. Fe Catalyst System
1.2.9. Ni Catalyst System
1.2.10. Mn Catalyst System
1.2.11. Transition Metal-Free Catalyst System
1.3. Heterogeneous Catalyst System
1.3.1. Cu Catalyst System
1.3.2. Ni Catalyst System
1.3.3. Fe/Mn/Co Catalyst Systems
1.3.4. Ru Catalyst System
1.3.5. Pd Catalyst System
1.3.6. Pt Catalyst System
1.3.7. Au Catalyst System
1.3.8. Ag Catalyst System
1.3.9. Transition Metal-Free Catalyst System
1.5. Conclusions and Outlook
Chapter 2: N-Alkyl Amine Synthesis by Catalytic Coupling of Amines
2.2. Homogeneous Catalyst System
2.2.1. Ir Catalyst System
2.2.2. Ru Catalyst System
2.2.3. Pt Catalyst System
2.2.4. Co Catalyst System
2.3. Heterogeneous Catalyst System
2.3.1. Pd Catalyst System
2.3.2. Pt Catalyst System
2.3.3. Ni Catalyst System
2.3.4. Cu Catalyst System
2.4. Conclusions and Outlook
Chapter 3: N-Alkyl Amine Synthesis by Hydroamination of Alkene and Diene
3.2. Intermolecular Hydroamination of Alkenes
3.2.1. Alkali and Alkaline Earth Metal-Based Catalysts
3.2.2. Rare Earth Metal-Based Catalysts
3.2.3. Late Transition Metal-Based Catalysts
3.2.3.1. Rh Catalyst System
3.2.3.2. Pd Catalyst System
3.2.3.3. Ir Catalyst System
3.2.3.4. Ru Catalyst System
3.2.3.5. Ni Catalyst System
3.2.3.6. Pt Catalyst System
3.2.3.7. Au Catalyst System
3.3. Asymmetric Intermolecular Hydroamination of Alkenes
3.3.1. Rare Earth Metal Catalysts
3.3.2. Late Transition Metal-Based Catalysts
3.3.2.1. Ir Catalyst System
3.3.2.2. Pd Catalyst System
3.3.2.3. Au Catalyst System
3.4. Intramolecular Hydroamination of Aminoalkenes
3.4.1. Alkali and Alkaline Earth Metal-Based Catalysts
3.4.2. Rare Earth Metal-Based Catalysts
3.4.3. Group 4/5 Metal-Based Catalysts
3.4.4. Late Transition Metal-Based Catalysts
3.4.4.1. Pt Catalyst System
3.4.4.2. Pd Catalyst System
3.4.4.3. Au Catalyst System
3.4.4.4. Rh Catalyst System
3.4.4.5. Ir Catalyst System
3.4.4.6. Cu and Fe Catalyst Systems
3.5. Asymmetric Intramolecular Hydroamination of Aminoalkenes
3.5.1. Alkali Metal and Alkaline Earth Metal-Based Catalysts
3.5.2. Rare Earth Metal-Based Catalysts
3.5.2.1. Clopentadienyl-Based Ligand
3.5.3. Group 4/5 Metal-Based Catalysts
3.5.4. Late Transition Metal-Based Catalysts
3.5.4.1. Pd Catalyst System
3.5.4.2. Rh Catalyst System
3.5.4.3. Au Catalyst System
3.5.4.4. Cu Catalyst System
3.5.5. Acid Catalyst Systems
3.6. Conclusions and Outlook
Chapter 4: N-Alkyl Amine Synthesis by Hydroaminomethylation
4.2. Intermolecular Hydroaminomethylation
4.2.1. Fe Catalyst System
4.2.2. Rh Catalyst System
4.2.2.1. Unmodified Rhodium Catalyst System
4.2.2.3. P,N-Ligands and Carbene Ligands
4.2.2.4. Heterogeneous and Semiheterogeneous Catalyst System
4.2.3. Co Catalyst System
4.2.4. Ru Catalyst System
4.2.5. Ir Catalyst System
4.2.6. Au Catalyst System
4.3. Intramolecular Hydroaminomethylation
4.4. Asymmetric Intermolecular Hydroaminomethylation
4.5. Asymmetric Intramolecular Hydroaminomethylation
4.6. Conclusions and Outlook
Chapter 5: N-Methyl Amine Synthesis by Reductive Amination of CO2
5.2. N-Methyl Amine Synthesis From CO2 and Amines
5.2.1. Hydrogen as Reducing Agent
5.2.1.1. Cu Catalyst System
5.2.1.2. Ru Catalyst System
5.2.1.3. Pd Catalyst System
5.2.1.4. Pt Catalyst System
5.2.1.5. Au Catalyst System
5.2.2. Hydrosilanes as Reducing Agent
5.2.2.1. Zn Catalyst System
5.2.2.2. Ru Catalyst System
5.2.2.3. Cu Catalyst System
5.2.2.4. Ni Catalyst System
5.2.2.5. Metal-Free Catalyst System
5.2.3. Boranes as Reducing Agent Under Transition Metal-Free Catalyst System
5.3. Conclusions and Outlook
Chapter 6: N-Alkyl Amine Synthesis by Oxidative Amination of Alkane
6.2. Intermolecular Oxidative Amination of Alkanes
6.2.1. Cu Catalyst System
6.2.2. Fe Catalyst System
6.2.3. Mn Catalyst System
6.2.4. Ru Catalyst System
6.2.5. Rh Catalyst System
6.2.6. Pd Catalyst System
6.2.7. Ag Catalyst System
6.2.8. Co Catalyst System
6.2.9. Re Catalyst System
6.2.10. Ni Catalyst System
6.2.11. Metal-Free System
6.3. Intramolecular Oxidative Amination of Alkanes
6.3.1. Cu Catalyst System
6.3.2. Fe Catalyst System
6.3.3. Mn Catalyst System
6.3.4. Ru Catalyst System
6.3.5. Rh Catalyst System
6.3.6. Pd Catalyst System
6.3.7. Ag Catalyst System
6.3.8. Co Catalyst System
6.3.9. Ni Catalyst System
6.3.10. Bimetal Catalyst System
6.3.11. Metal-Free Catalyst System
6.4. Conclusions and Outlook
Chapter 7: N-Alkyl Amine Synthesis With Nitroarene/Benzonitrile and Alcohol
7.2. Synthesis of N-Alkyl Amines From Nitroarenes and Alcohols
7.2.1. Alcohol as Reducing Agent
7.2.1.1. Ru Catalyst System
7.2.1.2. Au Catalyst System
7.2.1.3. Ni Catalyst System
7.2.1.4. Peroxide/TBP Catalyst System
7.2.1.5. Photocatalytic System
7.2.2. Glycerol as Reducing Agent
7.2.3. Hydrogen as Reducing Agent
7.3. Synthesis of N-Alkyl Amines From Benzonitriles and Alcohols
7.3.1. Alcohol as Reducing Agent
7.4. Conclusions and Outlook