Description
Advances in Organometallic Chemistry, Volume 69, contains authoritative review articles of world renowned researchers in the field of organometallic chemistry. This longstanding serial is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more, with this release focusing on topics such as C-H Activation Mediated by Main Group Inorganic and Organometallic Compounds, Transition-metals catalyzed intramolecular amination and hydroamination reactions of allenes, Green Fluorescent Protein-like and related organometallic fluorophores, Recent advances in the synthesis of C- S- bonds via metal‐catalyzed functionalization of C‐ H‐ bonds, Current mechanistic understanding of Co-catalyzed C-H functionalization, and more.
The book is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications.
- Contains contributions from leading authorities in the field of organometallic chemistry
- Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more
- Informs and updates readers on the latest developments in the field
- Carefully edited to provide easy-to-read material
Chapter
3. Carboamination of Allenes
3.1. Palladium-Catalyzed Intermolecular Coupling/Intramolecular Amination Processes
3.2. Palladium-Catalyzed Intramolecular Coupling/Intramolecular Amination Processes
3.3. Transition Metal-Catalyzed Miscellaneous Carboaminations
4. Aminocarbonylation of Allenes
5. Diamination of Allenes
6. Aminohalogenation of Allenes
Chapter Two: Organometallic Fluorophores of d8 Metals (Pd, Pt, Au)
2. Palladium (II) Complexes
2.1. Azo- and Diazo-[CN]- and [CNN]-Mono(di)cyclopalladated Fluorophores
2.2. Schiff Base [CNN] Dicyclopalladated Fluorophores
2.3. [CN]- and [CNN] Mono- and Dicyclopalladated Fluorophores From Arylated Azaheterocycles
3. Platinum(II) Complexes
5. Conclusions and Outlook
Chapter Three: Recent Advances in the Synthesis of C-S Bonds via Metal-Catalyzed or -Mediated Functionalization of C-H Bonds
2. Synthesis of Thioether, Thiols, and Disulfides
2.1. Cu-Catalyzed or -Mediated Reactions
2.2. Pd-Catalyzed Reactions
2.3. Ni-Catalyzed Reactions
2.4. Rh-Catalyzed Reactions
2.5. Ru-Catalyzed Reactions
2.6. Reactions Catalyzed by Other Metals
3. Synthesis of Sulfoxides, Sulfonamides, and Sulfoximines
4.1. Pd-Catalyzed Reactions
4.2. Cu-Catalyzed or -Mediated Reactions
4.3. Ni-Catalyzed Reactions
4.4. Ru- and Rh-Catalyzed Reactions
4.5. Reactions Catalyzed by Other Metals
5. Synthesis of Sulfur-Containing Heterocycles
5.1. Pd-Catalyzed Reactions
5.2. Cu-Catalyzed Reactions
5.3. Ru- and Rh-Catalyzed Reactions
5.4. Reactions Catalyzed by Other Metals
6. Conclusion and Outlook
Chapter Four: Current Mechanistic Understanding of Cobalt-Catalyzed C-H Functionalization
2. Early Examples of Cobalt-Catalyzed C-H Functionalization Reactions
3. Low-Valent Cobalt-Mediated C-H Activation
3.1. Modern Low-Valent Cobalt-Catalyzed C-H Activation
4. High-Valent Cobalt-Mediated C-H Activation
4.1. Early Stoichiometric Examples
4.2. Half-Sandwich Cobalt(III) C-H Functionalization
4.2.1. Examples and Applications of Cp*Co(III) Catalysts Used in C-H Functionalization Protocols
4.3. Oxidative C-H Activation and Functionalization
4.3.1. C-H Activation and Functionalization with Alkynes, Alkenes, and Allenes: From Migratory Insertion to Other Unique ...
4.3.2. Insertion of Carbon Monoxide Through Co(I)/Co(III) and Co(II)/Co(IV) Catalysis
4.3.3. C-H Arylation and Alkylation: Discrimination Between Electrophilic Pathways and Co(I)/Co(III) or Co(II)/Co(IV) Routes
4.3.4. Mechanistic Pathways in Cobalt-Catalyzed C-H Amination and Esterification
5. Cobalt-Catalyzed C-H Functionalization Through One-Electron Processes
Chapter Five: Metallate Complexes of the Late Transition Metals: Organometallic Chemistry and Catalysis
3.1.1. Reactions Catalyzed by Cobalt Carbonyl Species
3.1.2. Reactions Catalyzed by Cobalt Alkyl Species
3.1.3. Reactions Catalyzed by Cobalt Aryloxide Complexes
3.1.4. Reactions Catalyzed by Cobalt Complexes Bearing Phosphine Ligands
3.1.5. Reactions Catalyzed by Cobalt Complexes Bearing Diene Ligands
3.1.6. Reactions Catalyzed by Cobalt Complexes Bearing Amine Ligands
3.1.7. Reactions Catalyzed by Cobalt Complexes Bearing N-Heterocyclic Carbene Ligands
3.2.1. Reactions Catalyzed by Rhodium Carbonyl Complexes
3.2.2. Reactions Catalyzed by Ionic Rhodium Complexes Bearing Diamine Ligands
3.2.3. Reactions Catalyzed by Rhodium-Quinonoid Complexes
3.2.4. Reactions Catalyzed by Diarylrhodates
3.3.1. Reactions Catalyzed by Iridium Carbonyl Complexes
3.3.2. Reactions Catalyzed by Iridium Quinonoid Complexes
3.3.3. Reactions Catalyzed by Iridium Complexes Bearing a Bipyridonate Ligand
Advances in Organometallic Chemistry
( Volume 69 )
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