Silica and Clay Dispersed Polymer Nanocomposites :Preparation, Properties and Applications ( Woodhead Publishing Series in Composites Science and Engineering )

Publication subTitle :Preparation, Properties and Applications

Publication series :Woodhead Publishing Series in Composites Science and Engineering

Author: Rahman   Md Rezaur  

Publisher: Elsevier Science‎

Publication year: 2018

E-ISBN: 9780081021309

P-ISBN(Paperback): 9780081021293

Subject: TB383 Keywords special structure material

Keyword: 工程材料学

Language: ENG

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Description

The production of ‘polymer nanocomposites’ has recently gained considerable attention from both the academic and industrial community, especially in the area of nanoscience. This is mainly due to their enhanced improvements in physico-mechanical, thermal and barrier properties compared to micro and more conventional composites. Their nanoscale dimensions, biodegradable character, cost-effectiveness and sustainability have constituted a stimulus for this increasing interest. Currently there is no limit to the possibility of applications. However, despite all this progress, it is still difficult to achieve uniform dispersion between the filler and the matrix, as agglomerations form far too easily and the production of polymer nanocomposites with high mechanical and thermal properties is still limited.

The authors of this proposed book, are of the opinion, that with the increase in scientific publications and the rapid progress in processing possibilities to produce nanocomposites based on various nanoscale fillers (silica/clay), a book that collects all of these scientific findings in one place would be timely and of great interest to both students and scientific researchers, who are concerned with the production, and application of nanocomposites as new innovative materials.

The authors aim is to present the latest research findings on the fabrication, properties and applications of nanofillers as reinforcement in polymer nanocomposites. Particular emphasis wi

Chapter

1.3. Scope of the study

1.4. Objectives of the study

1.5. Literature review

1.5.1. Clays and clay minerals

1.5.2. Modifications of clay to enhance the properties of nanocomposites

1.5.2.1. Modification of clay by Silane reaction

1.5.2.2. Modification of clay by ion-exchange with organic cations

1.5.3. Structure of nanocomposites

1.5.4. Polymer nanocomposites

1.5.4.1. PVA-silica/fumed silica nanocomposites

1.5.4.2. PVA-clay nanocomposites

1.5.4.3. PF-fumed silica nanocomposites

1.5.4.4. PF-clay nanocomposites

1.5.4.5. ST-co-GMA-fumed silica nanocomposites

1.5.4.6. ST-co-GMA-clay nanocomposites

1.5.4.7. PLA-fumed silica nanocomposites

1.5.4.8. PLA-clay nanocomposites

1.5.5. The changes in properties of silica and clay nanocomposites

1.5.5.1. Physical properties of silica/fumed silica nanocomposites

1.5.5.2. Physical properties of clay nanocomposites

1.5.5.3. Mechanical properties of silica/fumed silica nanocomposites

1.5.5.4. Mechanical properties of clay nanocomposites

1.5.5.5. Thermal properties of silica/fumed silica nanocomposites

1.5.5.6. Thermal properties of clay nanocomposites

1.5.5.7. Water barrier properties of silica/fumed silica nanocomposites

1.5.5.8. Water barrier properties of clay nanocomposites

1.5.6. Techniques used to prepare polymer nanocomposites

1.5.6.1. Solution intercalation

1.5.6.2. Condensation polymerization

1.5.6.3. Free radical polymerization

1.5.6.4. Solution-intercalation film-casting

1.6. Conclusion

References

Chapter 2: Preparation and characterizations of silica and various clay dispersed nanocomposites

2.1. Materials

2.1.1. Polymers

2.1.2. Fillers

2.1.3. Chemicals

2.2. Preparations of nanocomposites

2.2.1. Preparation of PVA-fsi-clay and PVA-si-clay nanocomposites by solution intercalation technique

2.2.2. Preparation of PF-fsi-clay nanocomposites by condensation polymerization technique

2.2.3. Preparation of ST-co-GMA-fsi-clay nanocomposites by free radical polymerization technique

2.2.4. Preparation of PLA-fsi-clay nanocomposites by solution-intercalation film-casting technique

2.3. Fourier transform infrared spectroscopy analysis

2.4. X-ray fluorescence analysis

2.5. Scanning Electron microscopy analysis

2.6. Adsorption isotherm

2.7. Tensile testing

2.8. Thermogravimetric analysis

2.9. Moisture absorption test

2.10. Conclusion

Chapter 3: Impact of nanoclay on physicomechanical, morphological, optical, BET isotherm, and thermal analysis of polyvin ...

3.1. Introduction

3.2. Results and discussion

3.2.1. Spectral analysis

3.2.2. Scanning electron microscopy (SEM) analysis

3.2.3. Adsorption isotherm analysis

3.2.4. Tensile properties

3.2.5. Thermogravimetric analysis

3.3. Conclusion

References

Chapter 4: Polyvinyl alcohol/silica/clay nanocomposites: effect of clay on surface morphology, electrical and thermo-mech ...

4.1. Introduction

4.2. Results and discussion

4.2.1. Spectral analysis

4.2.2. X-ray fluorescence analysis

4.2.3. Scanning electron microscopy analysis

4.2.4. Adsorption isotherm analysis

4.2.5. Tensile properties

4.2.6. Thermogravimetric analysis

4.3. Conclusion

References

Chapter 5: Nanoclay dispersed phenol formaldehyde/fumed silica nanocomposites: effect of diverse clays on physicomechanic ...

5.1. Introduction

5.2. Results and discussion

5.2.1. Spectral analysis

5.2.2. X-ray fluorescence analysis

5.2.3. Scanning electron microscopy analysis

5.2.4. Adsorption isotherm analysis

5.2.5. Tensile properties

5.2.6. Thermogravimetric analysis

5.3. Summary

References

Chapter 6: Study on physical, mechanical, morphological and thermal properties of styrene-co-glycidyl methacrylate/fumed sil

6.1. Introduction

6.2. Results and discussion

6.2.1. Spectral analysis

6.2.2. Scanning electron microscopy analysis

6.2.3. Adsorption isotherm analysis

6.2.4. Tensile properties

6.2.5. Thermogravimetric analysis

6.2.6. Moisture absorption analysis

6.3. Summary

References

Chapter 7: Physico-mechanical and thermal properties of clay/fumed silica diffuse polylactic acid nanocomposites

7.1. Introduction

7.2. Results and discussion

7.2.1. Spectral (FTIR) analysis

7.2.2. X-ray fluorescence analysis

7.2.3. Scanning electron microscopy analysis

7.2.4. Adsorption isotherm analysis

7.2.5. Tensile properties

7.2.6. Thermogravimetric analysis

7.2.7. Moisture absorption analysis

7.3. Summary

References

Chapter 8: Biomedical and packaging application of silica and various clay dispersed nanocomposites

8.1. Introduction

8.2. Structure and characteristics of layered silicates and clays

8.3. Organic modification of layered silicates

8.4. Nanocomposite structure

8.5. Nanocomposite structural characterization

8.6. Nanocomposite mechanical properties

8.7. Toughness and strain

8.8. Flame retardance

8.9. Nanocomposites: Advantages and applications

References

Chapter 9: Durability and sustainability of the silica and clay and its nanocomposites

9.1. Introduction

9.2. The role of nanofillers on nanocomposites

9.3. Clay

9.4. Silica

9.5. Durability and sustainability of clay nanocomposites and silica nanocomposites

9.5.1. Spectral and thermal properties

9.5.2. Mechanical properties

9.5.3. Morphological properties

9.6. Challenges and applications

9.7. Summary

References

Further reading

Chapter 10: Low-density polyethylene/silica nanocomposites foams: Relationship between chemical composition, particle dis ...

10.1. Introduction

10.2. Chemical composition and physical properties

10.2.1. Fourier transform infrared spectroscopy (FTIR) analysis

10.3. Mechanical properties

10.4. Thermal properties

10.4.1. Thermogravimetric analysis (TGA)

10.4.2. Differential acanning calorimetry (DSC)

10.4.3. Dynamic mechanical thermal analysis (DMTA)

10.5. Scanning electron microscopy (SEM) study

10.6. Cellular structure of nanocomposite foams

10.7. Electrical properties (DC current)

References

Further reading

Chapter 11: The effect of clay dispersion on polypropylene nanocomposites: Physico-mechanical, thermal, morphological, a

11.1. Overview of the nanocomposites

11.2. Possibilities and prospects in nanocomposites

11.3. Preparation of nanocomposites

11.3.1. Raw materials

11.3.2. Preparation methods for ceramic nanocomposites

11.3.3. Ceramic matrix nanocomposites (CMNC)

11.3.4. Metal matrix nanocomposites (MMNC)

11.3.5. Preparation methods for metal matrix nanocomposites

11.3.6. Polymer matrix nanocomposites (PMNC)

11.3.7. Preparation methods for polymer-based nanocomposite systems

11.3.8. Conducting polymer nanocomposites preparation

11.3.9. Polymer matrix nanocomposites

11.3.10. Physical properties of nanocomposites

11.3.10.1. Fourier transform infrared spectroscopy (FTIR) analysis

11.3.11. Mechanical properties of nanocomposites

11.3.11.1. Tensile properties of nanoclay reinforced nanocomposites

11.3.11.2. Mechanical properties of layered reinforcement's nanocomposites

11.3.12. Thermal properties of nanocomposites

11.3.12.1. Thermogravimetric analysis (TGA) of nanocomposites

11.3.12.2. Differential scanning calorimetry (DSC)

11.3.12.3. Dynamic mechanical analysis (DMA)

11.3.13. Morphological properties of nanocomposites

11.3.13.1. Scanning electron microscopy (SEM) Analysis

11.3.14. Optical properties of nanocomposites

11.3.14.1. Optical properties of PP/Clay nanocomposites

References

Further reading

Chapter 12: Improvement of epoxy nanocomposites on physical, morphology, and mechanical properties as well as fracture be ...

12.1. Introduction

12.2. Nanocomposites and nanofillers

12.3. Epoxy

12.4. Mesoporous silica/nano-silica

12.5. Physical and mechanical properties

12.6. Fracture behavior and morphological properties

12.7. Summary

References

Further reading

Index

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