Chapter
8 The NifS/NifU [Fe-S] Cluster Assembly Toolkit Provides a Paradigm for Simple [Fe-S] Cluster Assembly
9 Functional Cross Talk Between [Fe-S] Cluster Biosynthetic Systems
13 Abbreviations and Acronyms
Iron-Sulfur Cluster Assembly in Bacteria and Eukarya using the ISC Biosynthesis Machinery
2 Core Fe-S Cluster Assembly Step
3 Fe-S Cluster Transfer Step
4 From the Mitochondria to the Cytosol
7 Abbreviations and Acronyms
The Suf System in Archaea, Bacteria, and Eukaryotic Organelles
2 Bacterial Suf Pathways: Diverse Roles in Fe-S Cluster Biogenesis
3 Archaea and the Origin of the Suf Pathway
4 Eukaryotic Suf Systems: A Role for Suf in Plastid Organelles and in the Cytoplasm
7 Abbreviations and Acronyms
Roles of Class II Glutaredoxins in the Maturation of Fe-S Proteins
2 The Cellular Maturation of Fe-S Proteins in Model Organisms
3 Involvement of Glutaredoxins in the Maturation of Fe-S Proteins in Eukaryotes
4 Spectroscopic and Structural Data for Fe-S Bridged Complexes Involving Class II GRXs
5 Molecular Interactions Between Class II GRXs and their Partners
8 Abbreviations and Acronyms
Part 2 Assembly of Complex and Heterometallic Fe-S Cluster Active Sites
Nitrogenase Metallocluster Assembly
2 Properties of NifDK Metalloclusters
5 Biosynthesis of P Cluster
6 Discussion and Future Directions
9 Abbreviations and Acronyms
Metallocluster Assembly: Maturation of [FeFe]-Hydrogenases
2 The Metal Center of [FeFe]-Hydrogenases
3 A Protein Machinery for [FeFe]-Hydrogenase Maturation
5 Mechanism of Maturation of [FeFe]-Hydrogenases
6 Maturase-Free Chemical Maturation: A Unique Technological Tool
9 Abbreviations and Acronyms
CO Dehydrogenase and Acetyl-CoA Synthase
2 Maturation of Ni,Fe-CODHs
3 Maturation of Ni,Fe-Containing ACS
7 Abbreviations and Acronyms
Part 3 Assembly of Homometallic and Heterometalic Cu Cluster Active Sites
Assembly of Dinuclear Copper Center in Tyrosinases and Hemocyanins
2 Tyrosinase and Hemocyanin: An Overview
6 Plant Tyrosinase (Catechol Oxidase) and Molluskan and Arthropod Hemocyanin
9 Abbreviations and Acronyms
2 Overview of MCO Structure and Copper-Coordination Sites
3 MCOs In Vitro: Interconversion of Apo and Holo Forms and Their Stability
4 Copper Redox State as a Probe of Copper-Site Assembly: Fet3
5 The Bacillus subtilis CotA MCO: Tracking the Protein and Metal In Vivo and In Vitro
6 Cellular Trafficking of MCO Proteins and Prosthetic Group Copper
9 Abbreviations and Acronyms
Assembly of the Redox-Active Metal Centers of Cytochrome c Oxidase
2 Heme a Biosynthesis and Insertion
3 Assembly of the CuB Center
4 Assembly of the CuA Center
5 Metallation of Copper Chaperones Involved in CcO Assembly
7 Abbreviations and Acronyms
CuA and CuZ Center Assembly in Nitrous Oxide Reductase
2 The Enzyme Nitrous Oxide Reductase
3 Assembly of Copper Centers into Nitrous Oxide Reductase
7 Abbreviations and Acronyms
MoCu CO Dehydrogenase and its Active-Site Assembly
2 Chemolithoautotrophic Growth with CO
3 MoCu CO Dehydrogenase of Oligotropha carboxidovorans
4 CO Dehydrogenase Active-Site Assembly
5 Function of CoxG as Membrane Anchor
8 Abbreviations and Acronyms
Part 4 Assembly of Homometallic and Heterometallic Mn Clusters
Homo- and Heterometallic Dinuclear Manganese Proteins: Active Site Assembly
2 Homometallic Manganese Proteins and their Cofactor Assembly
3 Heterometallic Manganese-Iron Proteins and their Cofactor Assembly
7 Abbreviations and Acronyms
Biogenesis and Assembly of the CaMn4O5 Core of Photosynthetic Water Oxidases and Inorganic Mutants
1 Introduction: Brief History, Biogeological Impact
2 Structure and Evolution of PSII
4 Manganese Speciation and Redox Equilibria Relevant to Cells
10 Abbreviations and Acronyms
Part 5 Assembly of Homometallic and Heterometallic Ni Clusters
2 Accessory Proteins Required for Urease Active Site Assembly
5 Abbreviations and Acronyms
Insights into [NiFe]-Hydrogenase Active Site Metallocluster Assembly
2 The Accessory Protein Machinery
5 The Conformational Switch and Active Site Closure
10 Abbreviations and Acronyms
Part 6 Assembly of Cofactors for Binding Active-site Metal Centers
2 The Biosynthesis of the Molybdenum Cofactors
3 The Biosynthesis of the Molybdenum Cofactors in Humans
7 Abbreviations and Acronyms
2 Synthesis of Aminolevulinic Acid (ALA)
3 Conversion of ALA to Uroporphyrinogen III
4 Siroheme-Dependent (SHD) Pathway
5 Further Preparation for the Coproporphyrin and Protoporphyrin-Dependent Pathways
6 Coproporphyrin-Dependent (CPD) Pathway
7 Protoporphyrin-Dependent (PPD) Pathway
8 Parasite Heme Biosynthesis
9 Regulation of Heme Synthesis
10 Future Directions in Heme Synthesis
13 Abbreviations and Acronyms
Siroheme Assembly and Insertion to Nitrite and Sulfite Reductase
2 Siroheme Biogenesis: CysG
5 Abbreviations and Acronyms
Biosynthesis of Coenzyme F430 and the Posttranslational Modification of the Active Site Region of Methyl-Coenzyme M Reductase
2 Coenzyme F430 Biosynthesis
3 MCR Posttranslational Modifications
7 Abbreviations and Acronyms
Coenzyme B12 Biosynthesis in Bacteria and Archaea
2 De Novo Corrin Ring Biosynthesis
3 The Nucleotide Loop Assembly (NLA) Pathway
4 Salvaging Complete and Incomplete Corrinoids
5 Biosynthesis of DMB and other Benzimidazoles
9 Abbreviations and Acronyms
Crosslinked Cys-Tyr Free Radical Redox Cofactor
2 Cys-Tyr Copper Metalloradical Active Site
3 Cofactor Self-Processing Reaction
7 Abbreviations and Acronyms
Topaquinone Biogenesis and Lysyl Tyrosine Quinone Biogenesis in Cu Amine Oxidases
2 Structural Background and Key Insights
3 Mechanistic Studies and the Characterization of Intermediates in TPQ Biogenesis
5 Inorganic Reactivity Considerations
8 Abbreviations and Acronyms
Metalloprotein Active Site Assembly
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