Developments in Electrochemistry: The Phase-Shift Method and Correlation Constants for Determining the Electrochemical Adsorption Isotherms at Noble and Highly Corrosion-Resistant Metal/Solution Interfaces ( Developments in Electrochemistry )

Publication series ： Developments in Electrochemistry

Author： Jinyoung Chun and Jang H. Chun  

Publisher： IntechOpen‎

Publication year： 2012

E-ISBN: INT5514852494

P-ISBN(Paperback): 9789535108511

P-ISBN(Hardback):  9789535108511

Subject： O646 electrochemical, electrolysis, chemical

Keyword： 电化学、电解、磁化学

Language： ENG

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Developments in Electrochemistry: The Phase-Shift Method and Correlation Constants for Determining the Electrochemical Adsorption Isotherms at Noble and Highly Corrosion-Resistant Metal/Solution Interfaces

Chapter

Developments in Electrochemistry: The Phase-Shift Method and Correlation Constants for Determining the Electrochemical Adsorption Isotherms at Noble and Highly Corrosion-Resistant Metal/Solution Interfaces

1. Introduction

2. Experimental

2.1. Preparations

2.2. Measurements

3. Results and discussion

3.1. Theoretical and experimental backgrounds of the phase-shift method

3.2. Basic procedure and description of the phase-shift method

3.3. Frumkin, Langmuir, and Temkin adsorption isotherms

3.4. Applicability of the Frumkin, Langmuir, and Temkin adsorption isotherms

3.5. Standard Gibbs energy of adsorption

4. Comparisons

4.1. Mixture solution

4.2. Correlation constants between the adsorption isotherms

4.3. Negative and positive values of the interaction parameters for the Frumkin adsorption isotherms

4.4. Equilibrium constants

5. Conclusions

Author details

References

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