Progress in Boron Chemistry ：Volume 3

Publication subTitle ：Volume 3

Author： Brotherton   R. J.;Steinberg   H.  

Publisher： Elsevier Science‎

Publication year： 2016

E-ISBN: 9781483146355

P-ISBN(Paperback): 9780080130804

Subject： O623.8 aliphatic sulfur compounds

Keyword： 化学

Language： ENG

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Description

Progress in Boron Chemistry, Volume 3 discusses the chemistry and applications of boron and its compounds. This book offers a detailed treatment of five areas of boron chemistry.
Organized into five chapters, this volume begins with an overview of the use of boric acid to favor alcohol formation in the air oxidation of hydrocarbons. This text then explains the standard procedure for hydrocarbon oxidation, which consists of passing air or a dilute oxygen in nitrogen stream via a suspension of boric acid in the heated substrate. Other chapters describe the radical-catalyzed addition of carbon tetrachloride to dibutyl vinylboronate and examine the growing interest in boron–nitrogen chemistry. This book discusses as well the polar addition of hydrogen bromide to unsaturated boronic esters. The final chapter deals with the chemical properties of organic boron–sulfur compounds.
This book is a valuable resource for chemists, organic chemists, students, and research workers.

Chapter

Front Cover

Progress in Boron Chemistry

Copyright Page

Table of Contents

Contributors to Volume 3

Preface

Chapter 1. OXIDATIONS OF ORGANIC SUBSTRATES IN THE PRESENCE OF BORON COMPOUNDS

I. INTRODUCTION

II. MECHANISMS OF OXIDATION REACTIONS

III. OXIDATIONS WITH MOLECULAR OXYGEN

IV. OXIDATIONS WITH OTHER OXIDIZING AGENTS OTHER THAN OXYGEN

V. CATALYTIC OXIDATION REACTIONS

VI. BORON COMPOUNDS AS OXIDATION STABILIZERS OR ANTIOXIDANTS

VII. REFERENCES

Chapter 2. NEIGHBORING - GROUP EFFECTS OF BORON IN ORGANOBORON COMPOUNDS

I. INTRODUCTION

II. THEORETICAL DESCRIPTION OF CARBON—BORON π-BONDING

III. BORON-SUBSTITUTED FREE RADICALS

IV. BORON-SUBSTITUTED ELECTROPHILIC CENTERS

V. BORON-SUBSTITUTED NUCLEOPHILIC CENTERS

VI. REFERENCES

Chapter 3. THERMOCHEMISTRY OF BORON COMPOUNDS

I. INTRODUCTION

II. THERMOCHEMICAL DATA

III. COLLATED STANDARD ENTHALPIES OF FORMATION

IV. DISCUSSION

V. REFERENCES

Chapter 4. SOME RECENT DEVELOPMENTS IN BORON-NITROGEN CHEMISTRY

I. INTRODUCTION

II. THE COORDINATE BORON-NITROGEN BOND

III. AMINE-BORON CATIONS

IV. THE CHEMISTRY OF SIMPLE BORON-NITROGEN COMPOUNDS

V. B-N-N- AND PYRAZABOLE CHEMISTRY

VI. MONOMERIC BORON IMIDES

VII. REFERENCES

Chapter 5. ORGANIC BORON-SULFUR COMPOUNDS

I. INTRODUCTION

II. ORTHO- AND METATHIOBORATES

III. THIOBORONATES AND THIOBORINATES

IV. B-ALKYLTHIOBORAZINE

V. 1,2-THIABOROLANES

VI. ALKYLTHIOBORANES

VII. DIALKYLAMINO(ALK YLTHIO) BORANES

VIII. CONCLUSIONS

IX. REFERENCES

NAME INDEX

SUBJECT INDEX

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