Progress in Boron Chemistry ：Volume 2

Publication subTitle ：Volume 2

Author： Brotherton R. J.;Steinberg H.

Publisher： Elsevier Science‎

Publication year： 2016

E-ISBN: 9781483146614

P-ISBN(Paperback): 9780080130798

Subject： O623.8 aliphatic sulfur compounds

Keyword：化学

Language： ENG

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Description

Progress in Boron Chemistry, Volume 2 presents the chemistry and applications of boron and its compounds. This book provides a critical treatment of six areas of boron chemistry, including polyhedral borane ions, carboranes, polymers, hydrogen, metal borides, and elemental boron.
Organized into six chapters, this volume begins with an overview of the structures as well as the synthesis of polyhedral borane anions. This text then examines the various types of classes and series of the carboranes. Other chapters consider the relatively intramolecular rearrangements and intramolecular exchange reactions concerning the various closo-carboranes and nido-carboranes. This book discusses as well the formation and the historical significance of a higher boron hydride polymer. The final chapter deals with the structural utilization of boron filaments, which promises to be the first large-scale use for comparatively high purity elemental boron.
This book is intended to be suitable for boron chemists, chemical engineers, scientists, and research workers.

Chapter

Front Cover

Progress in Boron Chemistry

Table of Contents

CONTRIBUTORS TO VOLUME 2

PREFACE

CHAPTER 1. THE CHEMISTRY OF POLYHEDRAL BORANE IONS

I. INTRODUCTION

II. SYNTHESIS AND STRUCTURES OF POLYHEDRAL BORANE ANIONS

III . ELECTROPHILIC SUBSTITUTION REACTIONS OF B10H2-10– AND B12H2-12

IV. ACID-CATALYZED NUCLEOPHILIC SUBSTITUTION REACTIONS

V. PHOTOCHEMICAL REACTIONS

VI. OXIDATIVE COUPLING OF B10H2-10– AND B12H2-12

VII. POLYHEDRAL ISOMERIZATION OF B10HfiT AND B12Hf2~ DERIVATIVES

VIII. ACKNOWLEDGMENT

IX. REFERENCES

CHAPTER 2. CARBORANES

I. INTRODUCTION AND BACKGROUND

II. CLASSIFICATION AND STRUCTURES

III. EXCHANGE REACTIONS, REARRANGEMENTS, AND DISPROPORTIONATIONS

IV. CARBORANE SYNTHESES

V. MASS SPECTROSCOPY

VI. NUCLEAR MAGNETIC RESONANCE

VII. REACTIONS AND DERIVATIVES

VIII. ACKNOWLEDGMENT

IX. NOTES ADDED IN PROOF

X. REFERENCES

CHAPTER 3. POLYMERS CONTAINING CLUSTERS OF BORON ATOMS

REFERENCES

CHAPTER 4. USE OF ISOTOPIC LABELS IN THE STUDY OF CARBORANES AND BINARY COMPOUNDS OF BORON AND HYDROGEN

I. INTRODUCTION

II. STUDIES INVOLVING BINARY COMPOUNDS OF BORON AND HYDROGEN

III. EXCHANGES INVOLVING IONIC COMPOUNDS

IV. ISOTOPIC EXCHANGES WITH CARBORANES

V. ISOTOPICALLY SUBSTITUTED MOLECULES IN SPECTRAL STUDIES

ACKNOWLEDGMENT

APPENDIX

REFERENCES

CHAPTER 5. THE CHEMISTRY OF METAL BORIDES AND RELATED COMPOUNDS

I. INTRODUCTION

II. CLASSIFICATION

III. STRUCTURE

IV. PREPARATION

V. PURIFICATION

VI. PROPERTIES

VII. REFERENCES

CHAPTER 6. ELEMENTAL BORON; PREPARATION, PROPERTIES AND APPLICATIONS

I. INTRODUCTION

II. PREPARATION

III. PROPERTIES

IV. APPLICATIONS

V. REFERENCES

NAME INDEX

SUBJECT INDEX

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