Front Cover

Iron, Ruthenium, and Osmium

Copyright Page

Table of Contents

Preface

Preface to 'Comprehensive Organometallic Chemistry'

Contributors to Volume 7

Abbreviations

Contents of All Volumes

Chapter 1. Iron Compounds without Hydrocarbon Ligands

1.1 INTRODUCTION

1.2 SIMPLE CARBONYLS AND CARBONYL ANIONS

1.3 IRON CARBONYL HYDRIDES

1.4 REACTIVE IRON CARBONYL FRAGMENTS

1.5 SUPPORTED IRON CARBONYL COMPOUNDS

1.6 IRON ISOCYANIDE COMPOUNDS

1.7 IRON THIOCARBONYL COMPOUNDS

1.8 IRON COMPOUNDS WITH GROUP 13 LIGANDS

1.9 IRON COMPOUNDS WITH GROUP 14 LIGANDS

1.10 IRON COMPOUNDS WITH GROUP 15 LIGANDS

1.11 IRON COMPOUNDS WITH GROUP 16 LIGANDS

1.12 IRON COMPOUNDS WITH HALIDE LIGANDS

1.13 IRON COMPOUNDS WITH THE POSTTRANSITION SERIES ELEMENTS

1.14 IRON COMPOUNDS WITH OTHER TRANSITION METALS

1.15 IRON COMPOUNDS IN CATALYSIS

1.16 REFERENCES

Chapter 2. Mononuclear Iron Compounds with η1-η6 Hydrocarbon Ligands

2.1 INTRODUCTION

2.2 REACTIONS OF IRON IONS AND ATOMS WITH ORGANICS

2.3 COMPOUNDS WITH η1-LIGANDS

2.4 COMPOUNDS WITH η2-LIGANDS

2.5 COMPOUNDS WITH η3-LIGANDS

2.6 COMPOUNDS WITH η4-LIGANDS

2.7 COMPOUNDS WITH ONE η5-LIGAND

2.8 FERROCENES

2.9 COMPOUNDS WITH η6-LIGANDS

2.10 OTHER REFERENCE WORKS

2.11 REFERENCES

Chapter 3. Dinuclear Iron Compounds with Hydrocarbon Ligands

3.1 INTRODUCTION

3.2 Fp2 AND RELATED COMPLEXES

3.3 COMPLEXES WITH LOW-HAPTICITY CARBON LIGANDS

3.4 COMPLEXES WITH SIGMA CARBON BRIDGES

3.5 BRIDGING η1,η2-, η1,η3-, AND η1,η5-LIGANDS

3.6 BRIDGING η1',η1,η2,η2-LIGANDS

3.7 COMPLEXES WITH HIGH-HAPTICITY CARBON LIGANDS

3.8 CATALYSIS AND MISCELLANEOUS

3.9 REFERENCES

Chapter 4. Polynuclear Iron Compounds with Hydrocarbon Ligands

4.1 CLUSTERS DERIVED FROM ALKYNES

4.2 CARBIDE CLUSTERS AND RELATED CLUSTER COMPOUNDS

4.3 CLUSTERS CONTAINING AN η1 - OR μ2-LIGAND

4.4 POLYIRON COMPOUNDS CONTAINING η-C5R5 GROUPS AS SUPPORTING LIGANDS

4.5 REFERENCES

Chapter 5. Introduction to Organoruthenium and Organoosmium Chemistry

5.1 INTRODUCTION

5.2 MONONUCLEAR COMPLEXES WITH ORGANIC LIGANDS

5.3 BINUCLEAR COMPLEXES

5.4 TRI-, TETRA- AND HIGHER-NUCLEARITY CLUSTERS

5.5 LITERATURE COVERAGE

5.6 STARTING MATERIALS

5.7 REFERENCES

Chapter 6. Mononuclear Complexes of Ruthenium and Osmium Containing η1 Carbon Ligands

6.1 COMPLEXES WITH M-C MULTIPLE BONDING: CARBONYL, CHALCOCARBONYL AND ISOCYANIDE COMPLEXES

6.2 COMPLEXES WITH M-C MULTIPLE BONDING: ALKYLIDENES, VINYLIDENES, ALKYLIDYNES AND RELATED LIGANDS

6.3 CARBONYL HYDRIDES AND RELATED COMPLEXES

6.4 σ-HYDROCARBYL COMPLEXES

6.5 REFERENCES

Chapter 7. Complexes of Ruthenium and Osmium Containing η2- η6 Hydrocarbon Ligands: (i) Complexes not Containing Cyclobutadiene, Cyclopentadienyl or h-Arene Coligands

7.1 η2-ALKENE AND η2-ALKYNE COMPLEXES OF RUTHENIUM(0) AND OSMIUM(0)

7.2 η2-ALKENE AND η2-ALKYNE COMPLEXES OF RUTHENIUM(II) AND OSMIUM(II)6

7.3 η4-DIENE COMPLEXES OF RUTHENIUM(II) AND OSMIUM(II)

7.4 η4-DIENE COMPLEXES OF RUTHENIUM(0) AND OSMIUM(4)

7.5 COMPLEXES OF ο-QUINODIMETHANES (ο-XYLYLENES)

7.6 COMPLEXES OF η4-ENONES, CYCLOPENTADIENONES AND QUINONES

7.7 ACYCLIC η3-ALLYL COMPLEXES

7.8 η3-YNYL AND η3-ENYNYL COMPLEXES

7.9 η4-TRIMETHYLENEMETHANE COMPLEXES

7.10 ACYCLIC η5-PENTADIENYL COMPLEXES

7.11 REFERENCES

Chapter 8. Complexes of Ruthenium and Osmium Containing η2- η6 Hydrocarbon Ligands: (ii) Complexes Containing Four- and Five-membered Rings (Including MCp(arene) Complexes)

8.1 η4-CYCLOBUTADIENE COMPLEXES

8.2 HALF-SANDWICH η5-CYCLOPENTADIENYL COMPLEXES

8.3 CYCLOPENTADIENYL ARENE COMPLEXES

8.4 REFERENCES

Chapter 9. Complexes of Ruthenium and Osmium Containing η2- η6 Hydrocarbon Ligands: (iii) Complexes Containing Six-, Seven- and Eight-membered Rings

9.1 BIS(ARENE) COMPLEXES

9.2 HALF-SANDWICH η6-ARENE COMPLEXES

9.3 ARENE AND ARYNE COMPLEXES OF LOW HAPTICITY (η< 6)

9.4 COMPLEXES CONTAINING SEVEN- AND EIGHT-MEMBERED RINGS

9.5 REFERENCES

Chapter 10. Ruthenocenes and Osmocenes

10.1 INTRODUCTION

10.2 SYNTHESES

10.3 STRUCTURES

10.4 PHYSICAL PROPERTIES

10.5 REDOX PROPERTIES

10.6 ORGANIC CHEMISTRY

10.7 BIRUTHENOCENES AND HIGHER OLIGOMERS

10.8 TRI- AND TETRADECKER MOLECULES

10.9 REACTIONS WITH LEWIS ACIDS

10.10 RADIOCHEMISTRY

10.11 APPLICATIONS OF RUTHENOCENE DERIVATIVES

10.12 REFERENCES

Chapter 11. Binuclear Complexes of Ruthenium and Osmium Containing Metal-Metal Bonds

11.1 CARBONYL COMPLEXES (HYDROCARBON FREE)

11.2 CARBONYL COMPLEXES CONTAINING HYDROCARBON LIGANDS

11.3 OTHER BINUCLEAR CYCLOPENTADIENYL COMPLEXES

11.4 ARENE COMPLEXES

11.5 METAL ALKYLS, ARYLS AND RELATED COMPLEXES

11.6 REFERENCES

Chapter 12. Trinuclear Clusters of Ruthenium and Osmium: (i) Introduction and Simple Neutral, Anionic and Hydrido Clusters

12.1 INTRODUCTION AND SURVEY OF LIGANDS

12.2 TRINUCLEAR CLUSTERS OF RUTHENIUM AND OSMIUM WITH LIGANDS COORDINATED THROUGH HETERO ATOMS ONLY

12.3 REFERENCES

Chapter 13. Trinuclear Clusters of Ruthenium and Osmium: (ii) Hydrocarbon Ligands on Metal Clusters

13.1 σ-BONDED (η1) HYDROCARBONS

13.2 η2-HYDROCARBONS

13.3 η3- TO η8-HYDROCARBON LIGANDS

13.4 REFERENCES

Chapter 14. Trinuclear Clusters of Ruthenium and Osmium: (iii) Clusters with Metal-Carbon Bonds to Heteroatom Ligands

14.1 INTRODUCTION

14.2 GROUP 16 LIGANDS

14.3 GROUP 15 LIGANDS

14.4 COMPLEXES WITH GROUP 14 HETEROATOMS BOUND THROUGH CARBON

14.5 REFERENCES

Chapter 15. Tetranuclear Clusters of Ruthenium and Osmium

15.1 GENERAL OVERVIEW

15.2 CARBONYL COMPOUNDS

15.3 COMPOUNDS WITH CARBON LIGANDS OTHER THAN CARBON MONOXIDE

15.4 COMPOUNDS WITH BRIDGING CARBON-HETEROATOM DONOR LIGANDS

15.5 REFERENCES

Chapter 16. Medium- and High-nuclearity Clusters of Ruthenium and Osmium

16.1 INTRODUCTION

16.2 M5 CLUSTERS

16.3 M6 CLUSTERS

16.4 M7 CLUSTERS

16.5 M8 CLUSTERS

16.6 M9 CLUSTERS

16.7 M10 CLUSTERS

16.8 CLUSTERS CONTAINING MORE THAN 10 METAL ATOMS

16.9 REFERENCES

Author Index

Subject Index