Membrane-Based Separations in Metallurgy :Principles and Applications

Publication subTitle :Principles and Applications

Author: Jiang   Lan Ying;Na   Li  

Publisher: Elsevier Science‎

Publication year: 2017

E-ISBN: 9780128034279

P-ISBN(Paperback): 9780128034101

Subject: O6 Chemistry;TF Metallurgical Industry;X7 Processing and Comprehensive Utilization of Waste

Keyword: 化学,矿业工程

Language: ENG

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Description

Membrane-Based Separation in Metallurgy: Principles and Applications begins with basic coverage of the basic principles of the topic and then explains how membrane technology helps in the development of new environmentally friendly and sustainable metallurgical processes.

The book features the principles of metallurgical process and how widely the membrane-based technology has been applied in metallurgical industry, including the basic principles of membrane-based separation in terms of material science, membrane structure engineering, transport mechanisms, and module design, detailed metallurgical process flowcharts with emphasis on membrane separations, current process designs, and describes problems and provides possible solutions.

In addition, the book includes specific membrane applications, molecular design of materials, fine tuning of membrane’s multi-scale structure, module selection and process design, along with a final analysis of the environmental and economic benefits achieved by using these new processes.

  • Outlines membrane separation processes and their use in the field of metallurgy
  • Includes case studies and examples of various processes
  • Describes individual unit operations and sectors of extractive metallurgy in a clear and thorough presentation for students and engineers
  • Provides a quick reference to wastewater treatment using membrane technology in the metallurgical industry
  • Outlines the design of

Chapter

1.2 - Extractive Metallurgy

1.2.1 - Pyrometallurgy

1.2.2 - Hydrometallurgy

1.2.3 - Electrometallurgy

1.2.4 - Biometallurgy

1.3 - Current Status of Metallurgical Industry

1.3.1 - Progress in China

1.3.2 - European Metallurgical Renaissance

1.4 - Conclusions

Glossary and Symbols

References

Chapter 2 - Membrane-Based Separation

2.1 - Basics About Membrane-Based Separation

2.1.1 - Membrane and Membrane Separation

2.1.2 - Membrane Structure and Configuration

2.1.3 - Membrane Materials

2.1.3.1 - Polymers

2.1.3.2 - Metals

2.1.3.3 - Ceramics

2.1.3.4 - Composites

2.1.3.5 - Liquid

2.2 - Fundamentals of Some Technically Relevant Separations

2.2.1 - Hydraulic and Osmotic Pressure–Driven Processes

2.2.1.1 - Microfiltration and ultrafiltration

2.2.1.2 - Nanofiltration

2.2.1.3 - Forward osmosis, reverse osmosis, and pressure-retarded osmosis

2.2.2 - Processes Using Ion-Exchange Membranes

2.2.2.1 - Electrodialysis

2.2.2.2 - Diffusion dialysis

2.2.2.3 - Membrane electrolysis

2.2.3 - Gas Separation

2.2.4 - Membrane Contactor

2.2.4.1 - Membrane gas absorption

2.2.4.2 - Membrane extraction and its derivatives

2.2.4.3 - Membrane distillation

2.2.5 - Membrane Adsorption

2.2.6 - Membrane Reactor

2.3 - Brief History of Development

2.4 - Conclusions

Glossary and Symbols

Nomenclature

Greek Symbols

Subscripts

References

Part 2 - Membrane-Based Separation for Metallurgical Process Improvement and Wastewater Treatment

Chapter 3 - Ferrous Metallurgy

3.1 - Iron and Steel

3.1.1 - Introduction

3.1.2 - Treatment of Acidic Wastewater

3.1.3 - Oily Wastewater Treatment

3.1.4 - Coking Plant Wastewater Treatment

3.1.5 - Desalination for Integrated Wastewater

3.1.6 - Treatment of Smelting Waste Gas

3.2 - Chromium

3.2.1 - Introduction

3.2.2 - Application of Nanofiltration

3.2.3 - Other Membrane Separations

3.3 - Manganese

3.3.1 - Introduction

3.3.2 - Purification of Manganese Sulfide (MnSO4) Solution

3.4 - Conclusions

Glossary and Symbols

References

Chapter 4 - Heavy Nonferrous Metals

4.1 - Nickel

4.1.1 - Introduction

4.1.2 - Improvement of Ni Electrowinning

4.1.3 - Process Wastewater as Secondary Resource

4.2 - Copper

4.2.1 - Introduction

4.2.2 - Assisting Selective Leaching Using Electromembrane

4.2.3 - Improvement of Conventional Process Efficiency

4.2.4 - Treatment of Various Process Waste Liquids

4.2.5 - Integrated or Hybrid Systems and Industrial Level Applications

4.3 - Zinc and Lead

4.3.1 - Introduction

4.3.2 - New Process for Zinc Sulfate Purification

4.3.3 - Arsenic Removal From Nonferrous Pyrometallurgy Process

4.3.4 - Facilitating Chlorine Metallurgy

4.3.5 Industrial Level Applications in Process Wastewater Treatment

4.4 - Other Researches About Heavy Metal Wastewater Treatment

4.4.1 - Basic Unit Operations

4.4.2 - Integrated or Hybrid Processes

4.5 - Remediation of Heavy Metal Polluted Soil

4.5.1 - Introduction

4.5.2 - Conventional Operations

4.5.3 - Unconventional Application of Ion-Exchange Membranes for In situ Soil Remediation

4.6 - Groundwater Remediation

4.7 - Conclusions

Glossary and Symbols

References

Chapter 5 - Light Nonferrous Metals

5.1 - Lithium

5.1.1 - Introduction

5.1.2 - Lithium Recovery From Various Solutions

5.1.3 - Lithium Hydroxide Production

5.1.4 - Processing of Powder Material for Lithium Ion Battery

5.2 - Aluminum

5.2.1 - Introduction

5.2.2 - Modification of Carbonation Process

5.2.3 - Treatment of Red Mud Wastewater

5.2.4 - α-Alumina Powder Washing

5.2.5 - Treatment of Wastewater From Aluminum Electrolysis Plant

5.3 - Conclusions

Glossary and Symbols

References

Chapter 6 - Refractory Metals

6.1 - Molybdenum

6.1.1 - Introduction

6.1.2 - Concentration of Ammonium Molybdate Crystallization Mother Liquor

6.1.3 - Comprehensive Utilization of Wastewater from Ammonium Molybdate

6.2 - Titanium

6.2.1 - Introduction

6.2.2 - Recovery of Waste Acid Released in Hydrolysis Step

6.2.3 - Recovery of Waste Acid in Material Processing or Fabrication

6.2.4 - Purification of Titanium Tetrafluoride

6.3 - Tungsten

6.3.1 - Introduction

6.3.2 - Free Alkali Recovery

6.3.3 - Utilization of Ammonium Para-Tungstate Crystallization Mother Liquor

6.3.4 - Other Applications

6.3.4.1 - Preparation of sodium meta-tungstate

6.3.4.2 - Preparation of AMT

6.3.4.3 - Splitting of Na2SO4 by Electrodialysis to produce acid and alkaline

6.4 - Vanadium

6.4.1 - Introduction

6.4.2 - New Process for Vanadium Extraction From Stone Coal

6.5 - Zirconium

6.5.1 - Introduction

6.5.2 - Treatment of Wastewater in Zirconium Oxychloride Production

6.5.3 - Rinsing of Zirconium Oxide Nanoparticles

6.6 - Conclusions

Symbols and Nomenclature

References

Chapter 7 - Scattered and Rare Earth Metals

7.1 - Introduction

7.2 - Extraction Using Liquid Membrane for Mixed Rare Earth Enrichment

7.3 - Researches and/or Applications Addressing Specific Metal

7.3.1 - Indium

7.3.1.1 - Recovery of indium from metallurgical process

7.3.1.2 - Treatment of indium nanoparticles

7.3.2 - Rhenium

7.3.2.1 - Recovery of rhenium

7.3.3 - Lanthanum

7.3.3.1 - Recovery of lanthanum

7.3.4 - Europium

7.3.4.1 - Production of europium compounds by membrane electrolysis reduction

7.3.5 - Cerium

7.3.5.1 - Cerium oxidation by membrane electrolysis

7.3.6 - Other Metals

7.3.6.1 - Lutetium

7.3.6.2 - Yttrium

7.4 - Applications Common for Rare Earth Metallurgy

7.4.1 - Concentration by Pressure Driven Membrane Separation

7.5 - Wastewater Treatment

7.5.1 - Recovery of Ammonia-Nitrogen

7.5.2 - Acid Recovery

7.6 - Conclusions

Glossary and Symbols

References

Chapter 8 - Radioactive Metals

8.1 - Introduction

8.2 - Treatment of Leaching Solution (or Metal Extraction)

8.2.1 - Emulsion Liquid Membrane

8.3 - Metal Compound Production

8.3.1 - Application of Membrane Electrolysis

8.4 - Processing of Radioactive Wastes

8.4.1 - Fuel Recovery

8.4.2 - Partitioning of Minor Actinides and Fission Products

8.4.2.1 - Electrodeionization

8.4.2.2 - Membrane extraction

8.4.2.3 - Supported liquid membrane

8.4.3 - Membrane Process for LLW

8.4.4 - Caustic Recovery

8.5 - More Researches and Examples

8.6 - Conclusions

Glossary and Symbols

References

Chapter 9 - Noble Metals

9.1 - Introduction

9.2 - Acid Mine Drainage Wastewater

9.3 - Cyanide Barren Solution Treatment

9.4 - Metallurgical Wastewater

9.5 - New Developments

9.6 - Conclusions

Nomenclature

References

Chapter 10 - More Works on Waste Treatment and Process Improvement

10.1 - Waste Gas Treatment

10.1.1 - Gaseous Components Removal

10.1.2 - Dust Elimination

10.2 - Water Treatment

10.2.1 - Electroplating Wastewater

10.2.2 - Combination of Etching With Pickling

10.2.3 - Recycling of Metal-Working Fluids

10.2.4 - Advanced Wastewater Treatment

10.3 - Potential Applications in Hydrometallurgical Processes

10.4 - Conclusions

Glossary and Symbols

References

Part 3 - Development of Special Industrial Membranes for Metallurgy

Chapter 11 - Overview

References

Chapter 12 - Polymeric Membranes

12.1 - Nanofiltration

12.1.1 - General Strategies for Improving Nanofiltration Membrane Separation Efficiency

12.1.2 - Acid-Resistant Nanofiltration Membranes

12.1.3 - Alkali-Resistant Nanofiltration Membrane

12.1.4 - Oxidation-Resistant NF Membranes

12.2 - Ion-Exchange Membrane

12.2.1 - “Green” Synthesis of Anion-Exchange Membranes

12.2.2 - Membrane Stability Control

12.2.3 - Nanochannels Architecture and Modification

12.2.4 - Novel Membrane Formation Technologies

12.2.5 - Industrialization Status in China

12.3 - Materials and Membranes for Ultrafiltration

12.3.1 - Molecular Design for Reinforced Ultrafiltration

12.3.1.1 - Micellar-enchanced Ultrafiltration

12.3.1.2 - Water soluble polymer enhanced ultrafiltration

12.3.2 - Membrane Surface Design

12.3.2.1 - Polymer blending

12.3.2.2 - Nanoparticles

Glossary and Symbols

References

Chapter 13 - Membrane Contactor

13.1 - Membrane Distillation

13.1.1 - Membrane Development

13.1.2 - Molecular Design of Membrane Hydrophobicity

13.2 - Other Membrane Contactors

13.3 - Control of Pore-wetting State

13.4 - Modules and Commercial Products

Glossary and Symbols

References

Chapter 14 - Ceramic Membranes

14.1 - Introduction

14.2 - General Progress in Membrane Fabrication and Modification

14.2.1 - Porous Ceramic Membranes

14.2.1.1 - Sol–Gel Method

14.2.1.2 - Surface Modification

14.2.1.3 - Other Methods

14.2.2 - Gas Separation Membranes

14.3 - Application-Orientated Consideration for Porous Ceramic Membrane Fabrication

14.4 - Industrialization

14.5 - Perspectives

Glossary and Symbols

References

Chapter 15 - Metal Membranes

15.1 - Introduction

15.2 - Stainless Steel-Based Porous Metal Membrane

15.2.1 - Neat Stainless Steel Membranes

15.2.2 - Composite Membrane Using Stainless Steel Substrate

15.3 - Membranes Based on Metal Alloys

15.3.1 - Membrane Based on Titanium-Aluminum Alloys

15.3.2 - Membrane Based on Nickel–Aluminum Alloys

15.3.3 - Membrane Based on Iron–Aluminum Alloys

15.4 - Industrialization

15.5 - Conclusions

Glossary and Symbols

References

Index

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