Description
Advances in Organometallic Chemistry, Volume 68 contains authoritative review articles of worldwide known researchers in the field of organometallic chemistry. This updated volume includes new chapters that cover Water Oxidation at Base Metal Molecular Catalysts, Functionalization Of White and Red Phosphorus in the Coordination Sphere of Transition Metal Complexes, Carbon Dioxide Transition Metal Complexes, Synthesis and Reaction Chemistry of Alkylidene Complexes with Group 4 and 5 Transition Metals: Effective Catalysts for Olefin Metathesis Polymerization and the Other Organic Transformations, and Recent Advances in Heteroatom Stabilized Carbones and Their Metal Complexes.
This long-standing serial is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications.
- Contains contributions from leading authorities in the field of organometallic chemistry
- Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more
- Informs and updates readers on all the latest developments in the field
- Carefully edited to provide easy-to-read material
Chapter
2. Milestones in Carbon Dioxide Transition Metal Complexes
3. Spectroscopic Features
3.1. Vibrational Spectroscopy
4. Structural Characterization
4.1. Mononuclear Compounds
4.3. Polynuclear Compounds
5. Other Characterization Methods
Chapter Two: Synthesis and Reaction Chemistry of Alkylidene Complexes With Titanium, Zirconium, Vanadium, and Niobium: Ef ...
1. Introductory: Importance in Olefin Metathesis With Titanium Catalysts
2. Synthesis of Titanium-, Zirconium-Alkylidenes and Some Reactions
2.1. Synthesis of Titanium-, Zirconium-Alkylidene Complexes
2.2. Organic Transformation of Titanium or Zirconium Alkylidenes
3. Synthesis of Vanadium-Alkylidene Complexes and Some Reactions: (Imido)Vanadium(V)-Alkylidenes as Effective Catalysts f ...
3.1. Synthesis of Vanadium-Alkylidene Complexes and Some Reactions
3.2. ROMP of Cyclic Olefins by (Imido)Vanadium(V)-Alkylidene Catalysts
3.2.2. ROMP of Cyclic Olefins
4. Recent Examples in Synthesis of Niobium-Alkylidenes and Some Reactions
4.1. Niobium-Alkylidene Complexes Containing Cyclopentadienyl Ligands
4.2. Synthesis and Reaction Chemistry of Niobium-Alkylidene Complexes Without Cyclopentadienyl Ligands
Chapter Three: Recent Advances in Heteroatom-Stabilized Carbones and Their Metal Complexes
2. Syntheses, Structures, and Reactivities of Carbones Stabilized by Phosphorus, Sulfur, and Selenium Ligands
2.1. Two Chalcogen-Stabilized Carbones
2.2. Phosphorus- and Sulfur-Stabilized Carbones
2.3. C-Alkylated Carbones
2.4. Dicationic Salts of Carbones
3. Metal Carbone Complexes
3.1. Gold(I) Carbone Complexes
3.2. Multimetallic Cluster Complexes Stabilized by Multidentate Carbone
3.3. Proton-Argentated Complexes
3.4. Carbone Transfer Reagents
4. Catalytic Applications of Metal Carbone Complexes
5. Conclusions and Outlook
Chapter Four: High-Valent Cobalt-Catalyzed C–H Bond Functionalization
1.1. C–H Activation and C–H Functionalization
1.2. Cp*Rh(III)-Catalyzed C–H Bond Functionalization
1.3. Low-Valent Cobalt-Catalyzed C–H Bond Functionalization
1.4. Stoichiometric C–H Bond Activation by High-Valent Cobalt
2. Cp*Co(III)-Catalyzed C–H Bond Functionalization Reactions
2.2. C–C Bond-Forming Reactions
2.2.1. Addition to Polar Unsaturated Bonds
2.2.2. Reactions With C–C Double Bonds of Alkenes and Allenes
2.2.3. Reactions With C–C Triple Bond of Alkynes
2.2.3.2. Nucleophilic Addition to Directing Groups
2.2.3.3. Reactions With Oxidizing Directing Groups
2.2.3.4. Oxidative Cyclization Using External Oxidants
2.2.4. Other C–C Bond-Forming Reactions
2.3. C–N Bond-Forming Reactions
2.3.1. Reactions With Organic Azides
2.3.2. Reactions With Dioxazolones
2.3.3. Reactions With Other Nitrogen Sources
2.4. Other C–X Bond-Forming Reactions
2.4.1. C–O Bond-Forming Reactions
2.4.2. C–Halogen Bond-Forming Reactions
2.4.3. CS and CSe Bond-Forming Reactions
3. Other High-Valent Cobalt-Catalyzed C–H Bond Functionalization
3.1. Bidentate-Directing Group-Assisted C–H Bond Functionalization
Advances in Organometallic Chemistry
( Volume 68 )
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
