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Advances in Organometallic Chemistry

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Contents

Contributors

Preface

Chapter One: Spectroscopic and Structural Characterization of Carbon Dioxide Transition Metal Complexes

1. Introduction

2. Milestones in Carbon Dioxide Transition Metal Complexes

3. Spectroscopic Features

3.1. Vibrational Spectroscopy

3.2. Multinuclear NMR

4. Structural Characterization

4.1. Mononuclear Compounds

4.2. Binuclear Compounds

4.3. Polynuclear Compounds

5. Other Characterization Methods

6. Summary

Acknowledgments

References

Chapter Two: Synthesis and Reaction Chemistry of Alkylidene Complexes With Titanium, Zirconium, Vanadium, and Niobium: Ef ...

1. Introductory: Importance in Olefin Metathesis With Titanium Catalysts

2. Synthesis of Titanium-, Zirconium-Alkylidenes and Some Reactions

2.1. Synthesis of Titanium-, Zirconium-Alkylidene Complexes

2.2. Organic Transformation of Titanium or Zirconium Alkylidenes

3. Synthesis of Vanadium-Alkylidene Complexes and Some Reactions: (Imido)Vanadium(V)-Alkylidenes as Effective Catalysts f ...

3.1. Synthesis of Vanadium-Alkylidene Complexes and Some Reactions

3.2. ROMP of Cyclic Olefins by (Imido)Vanadium(V)-Alkylidene Catalysts

3.2.1. Introductory

3.2.2. ROMP of Cyclic Olefins

4. Recent Examples in Synthesis of Niobium-Alkylidenes and Some Reactions

4.1. Niobium-Alkylidene Complexes Containing Cyclopentadienyl Ligands

4.2. Synthesis and Reaction Chemistry of Niobium-Alkylidene Complexes Without Cyclopentadienyl Ligands

5. Summary and Outlook

References

Chapter Three: Recent Advances in Heteroatom-Stabilized Carbones and Their Metal Complexes

1. Introduction

2. Syntheses, Structures, and Reactivities of Carbones Stabilized by Phosphorus, Sulfur, and Selenium Ligands

2.1. Two Chalcogen-Stabilized Carbones

2.1.1. Syntheses

2.1.2. Structures

2.2. Phosphorus- and Sulfur-Stabilized Carbones

2.2.1. Syntheses

2.2.2. Structures

2.3. C-Alkylated Carbones

2.4. Dicationic Salts of Carbones

3. Metal Carbone Complexes

3.1. Gold(I) Carbone Complexes

3.2. Multimetallic Cluster Complexes Stabilized by Multidentate Carbone

3.3. Proton-Argentated Complexes

3.4. Carbone Transfer Reagents

4. Catalytic Applications of Metal Carbone Complexes

5. Conclusions and Outlook

Acknowledgments

References

Further Reading

Chapter Four: High-Valent Cobalt-Catalyzed C–H Bond Functionalization

1. Introduction

1.1. C–H Activation and C–H Functionalization

1.2. Cp*Rh(III)-Catalyzed C–H Bond Functionalization

1.3. Low-Valent Cobalt-Catalyzed C–H Bond Functionalization

1.4. Stoichiometric C–H Bond Activation by High-Valent Cobalt

2. Cp*Co(III)-Catalyzed C–H Bond Functionalization Reactions

2.1. Overview

2.2. C–C Bond-Forming Reactions

2.2.1. Addition to Polar Unsaturated Bonds

2.2.2. Reactions With C–C Double Bonds of Alkenes and Allenes

2.2.3. Reactions With C–C Triple Bond of Alkynes

2.2.3.1. Alkenylation

2.2.3.2. Nucleophilic Addition to Directing Groups

2.2.3.3. Reactions With Oxidizing Directing Groups

2.2.3.4. Oxidative Cyclization Using External Oxidants

2.2.4. Other C–C Bond-Forming Reactions

2.3. C–N Bond-Forming Reactions

2.3.1. Reactions With Organic Azides

2.3.2. Reactions With Dioxazolones

2.3.3. Reactions With Other Nitrogen Sources

2.4. Other C–X Bond-Forming Reactions

2.4.1. C–O Bond-Forming Reactions

2.4.2. C–Halogen Bond-Forming Reactions

2.4.3. CS and CSe Bond-Forming Reactions

3. Other High-Valent Cobalt-Catalyzed C–H Bond Functionalization

3.1. Bidentate-Directing Group-Assisted C–H Bond Functionalization

3.2. Other Reaction

4. Summary

References

Index

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