Geochronology and Thermochronology

Chapter

2.3 NUCLEAR STABILITY

2.3.1 Nuclear binding energy and the mass defect

2.3.2 The liquid drop model for the nucleus

2.3.3 The nuclear shell model

2.3.4 Chart of the nuclides

2.4 RADIOACTIVE DECAY

2.4.1 Fission

2.4.2 Alpha-decay

2.4.3 Beta-decay

2.4.4 Electron capture

2.4.5 Branching decay

2.4.6 The energy of decay

2.4.7 The equations of radioactive decay

2.5 NUCLEOSYNTHESIS AND ELEMENT ABUNDANCES IN THE SOLAR SYSTEM

2.5.1 Stellar nucleosynthesis

2.5.2 Making elements heavier than iron: s-, r-, p-process nucleosynthesis

2.5.3 Element abundances in the solar system

2.6 ORIGIN OF RADIOACTIVE ISOTOPES

2.6.1 Stellar contributions of naturally occurring radioactive isotopes

2.6.2 Decay chains

2.6.3 Cosmogenic nuclides

2.6.4 Nucleogenic isotopes

2.6.5 Man-made radioactive isotopes

2.7 CONCLUSIONS

2.8 REFERENCES

Chapter 3 Analytical methods

3.1 INTRODUCTION

3.2 SAMPLE PREPARATION

3.3 EXTRACTION OF THE ELEMENT TO BE ANALYZED

3.4 ISOTOPE DILUTION ELEMENTAL QUANTIFICATION

3.5 ION EXCHANGE CHROMATOGRAPHY

3.6 MASS SPECTROMETRY

3.6.1 Ionization

3.6.2 Extraction and focusing of ions

3.6.3 Mass fractionation

3.6.4 Mass analyzer

3.6.5 Detectors

3.6.6 Vacuum systems

3.7 CONCLUSIONS

3.8 REFERENCES

Chapter 4 Interpretational approaches: making sense of data

4.1 INTRODUCTION

4.2 TERMINOLOGY AND BASICS

4.2.1 Accuracy, precision, and trueness

4.2.2 Random versus systematic, uncertainties versus errors

4.2.3 Probability density functions

4.2.4 Univariate (one-variable) distributions

4.2.5 Multivariate normal distributions

4.3 ESTIMATING A MEAN AND ITS UNCERTAINTY

4.3.1 Average values: the sample mean, sample variance, and sample standard deviation

4.3.2 Average values: the standard error of the mean

4.3.3 Application: accurate standard errors for mass spectrometry

4.3.4 Correlation, covariance, and the covariance matrix

4.3.5 Degrees of freedom, part 1: the variance

4.3.6 Degrees of freedom, part 2: Student´s t distribution

4.3.7 The weighted mean

4.4 REGRESSING A LINE

4.4.1 Ordinary least-squares linear regression

4.4.2 Weighted least-squares regression

4.4.3 Linear regression with uncertainties in two or more variables (York regression)

4.5 INTERPRETING MEASURED DATA USING THE MEAN SQUARE WEIGHTED DEVIATION

4.5.1 Testing a weighted mean´s assumptions using its MSWD

4.5.2 Testing a linear regression´s assumptions using its MSWD

4.5.3 My data set has a high MSWD—what now?

4.5.4 My data set has a really low MSWD—what now?

4.6 CONCLUSIONS

4.7 Bibliography and Suggested Readings

Chapter 5 Diffusion and thermochronologic interpretations

5.1 FUNDAMENTALS OF HEAT AND CHEMICAL DIFFUSION

5.1.1 Thermochronologic context

5.1.2 Heat and chemical diffusion equation

5.1.3 Temperature dependence of diffusion

5.1.4 Some analytical solutions

5.1.5 Anisotropic diffusion

5.1.6 Initial infinite concentration (spike)

5.1.7 Characteristic length and time scales

5.1.8 Semi-infinite media

5.1.9 Plane sheet, cylinder, and sphere

5.2 FRACTIONAL LOSS

5.3 ANALYTICAL METHODS FOR MEASURING DIFFUSION

5.3.1 Step-heating fractional loss experiments

5.3.2 Multidomain diffusion

5.3.3 Profile characterization

5.4 INTERPRETING THERMAL HISTORIES FROM THERMOCHRONOLOGIC DATA

5.4.1 ``End-members´´ of thermochronometric date interpretations

5.4.2 Equilibrium dates

5.4.3 Partial retention zone

5.4.4 Resetting dates

5.4.5 Closure

5.5 FROM THERMAL TO GEOLOGIC HISTORIES IN LOW-TEMPERATURE THERMOCHRONOLOGY: DIFFUSION AND ADVECTION OF HEAT IN THE EARTH'S ...

5.5.1 Simple solutions for one- and two-dimensional crustal thermal fields

5.5.2 Erosional exhumation

5.5.3 Interpreting spatial patterns of erosion rates

5.5.4 Interpreting temporal patterns of erosion rates

5.5.5 Interpreting paleotopography

5.6 DETRITAL THERMOCHRONOLOGY APPROACHES FOR UNDERSTANDING LANDSCAPE EVOLUTION AND TECTONICS

5.7 CONCLUSIONS

5.8 REFERENCES

Chapter 6 Rb–Sr, Sm–Nd, and Lu–Hf

6.1 INTRODUCTION

6.2 HISTORY

6.3 THEORY, FUNDAMENTALS, AND SYSTEMATICS

6.3.1 Decay modes and isotopic abundances

6.3.2 Decay constants

6.3.3 Data representation

6.3.4 Geochemistry

6.4 ISOCHRON SYSTEMATICS

6.4.1 Distinguishing mixing lines from isochrons

6.5 DIVERSE CHRONOLOGICAL APPLICATIONS

6.5.1 Dating diagenetic minerals in clay-rich sediments

6.5.2 Direct dating of ore minerals

6.5.3 Dating of mineral growth in magma chambers

6.5.4 Garnet Sm–Nd and Lu–Hf dating

6.6 MODEL AGES

6.6.1 Model ages for volatile depletion

6.6.2 Model ages for multistage source evolution

6.7 CONCLUSION AND FUTURE DIRECTIONS

6.8 REFERENCES

Chapter 7 Re–Os and Pt–Os

7.1 INTRODUCTION

7.2 RADIOACTIVE SYSTEMATICS AND BASIC EQUATIONS

7.3 GEOCHEMICAL PROPERTIES AND ABUNDANCE IN NATURAL MATERIALS

7.4 ANALYTICAL CHALLENGES

7.5 GEOCHRONOLOGIC APPLICATIONS

7.5.1 Meteorites

7.5.2 Molybdenite

7.5.3 Other sulfides, ores, and diamonds

7.5.4 Organic-rich sediments

7.5.5 Komatiites

7.5.6 Basalts

7.5.7 Dating melt extraction from the mantle—Re–Os model ages

7.6 CONCLUSIONS

7.7 REFERENCES

Chapter 8 U–Th–Pb geochronology and thermochronology

8.1 INTRODUCTION AND BACKGROUND

8.1.1 Decay of U and Th to Pb

8.1.2 Dating equations

8.1.3 Decay constants

8.1.4 Isotopic composition of U

8.2 CHEMISTRY OF U, Th, AND Pb

8.3 DATA VISUALIZATION, ISOCHRONS, AND CONCORDIA PLOTS

8.3.1 Isochron diagrams

8.3.2 Concordia diagrams

8.4 CAUSES OF DISCORDANCE IN THE U–Th–Pb SYSTEM

8.4.1 Mixing of different age domains

8.4.2 Pb loss

8.4.3 Intermediate daughter product disequilibrium

8.4.4 Correction for initial Pb

8.5 ANALYTICAL APPROACHES TO U–Th–Pb GEOCHRONOLOGY

8.5.1 Thermal ionization mass spectrometry

8.5.2 Secondary ion mass spectrometry

8.5.3 Laser ablation inductively coupled plasma mass spectrometry

8.5.4 Elemental U–Th–Pb geochronology by EMP

8.6 APPLICATIONS AND APPROACHES

8.6.1 The age of meteorites and of Earth

8.6.2 The Hadean

8.6.3 P–T–t paths of metamorphic belts

8.6.4 Rates of crustal magmatism from U–Pb geochronology

8.6.5 U–Pb geochronology and the stratigraphic record

8.6.6 Detrital zircon geochronology

8.6.7 U–Pb thermochronology

8.6.8 Carbonate geochronology by the U–Pb method

8.6.9 U–Pb geochronology of baddeleyite and paleogeographic reconstructions

8.7 CONCLUDING REMARKS

8.8 REFERENCES

Chapter 9 The K–Ar and 40Ar/39Ar systems

9.1 INTRODUCTION AND FUNDAMENTALS

9.2 HISTORICAL PERSPECTIVE

9.3 K–AR DATING

9.3.1 Determining 40Ar*

9.3.2 Determining 40K

9.4 40AR/39AR DATING

9.4.1 Neutron activation

9.4.2 Collateral effects of neutron irradiation

9.4.3 Appropriate materials

9.5 EXPERIMENTAL APPROACHES AND GEOCHRONOLOGIC APPLICATIONS

9.5.1 Single crystal fusion

9.5.2 Intragrain age gradients

9.5.3 Incremental heating

9.6 CALIBRATION AND ACCURACY

9.6.1 40K decay constants

9.6.2 Standards

9.6.3 So which is the best calibration?

9.6.4 Interlaboratory issues

9.7 CONCLUDING REMARKS

9.7.1 Remaining challenges

9.8 REFERENCES

Chapter 10 Radiation-damage methods of geochronology and thermochronology

10.1 INTRODUCTION

10.2 THERMAL AND OPTICALLY STIMULATED LUMINESCENCE

10.2.1 Theory, fundamentals, and systematics

10.2.2 Analysis

10.2.3 Fundamental assumptions and considerations for interpretations

10.2.4 Applications

10.3 ELECTRON SPIN RESONANCE

10.3.1 Theory, fundamentals, and systematics

10.3.2 Analysis

10.3.3 Fundamental assumptions and considerations for interpretations

10.3.4 Applications

10.4 ALPHA DECAY, ALPHA-PARTICLE HALOES, AND ALPHA-RECOIL TRACKS

10.4.1 Theory, fundamentals, and systematics

10.5 FISSION TRACKS

10.5.1 History

10.5.2 Theory, fundamentals, and systematics

10.5.3 Analyses

10.5.4 Fission-track age equations

10.5.5 Fission-track annealing

10.5.6 Track-length analysis

10.5.7 Applications

10.6 CONCLUSIONS

10.7 REFERENCES

Chapter 11 The (U–Th)/He system

11.1 INTRODUCTION

11.2 HISTORY

11.3 THEORY, FUNDAMENTALS, AND SYSTEMATICS

11.4 ANALYSIS

11.4.1 ``Conventional´´ analyses

11.4.2 Other analytical approaches

11.4.3 Uncertainty and reproducibility in (U–Th)/He dating

11.5 HELIUM DIFFUSION

11.5.1 Introduction

11.5.2 Apatite

11.5.3 Zircon

11.5.4 Other minerals

11.5.5 A compilation of He diffusion kinetics

11.6 4He/3He THERMOCHRONOMETRY

11.6.1 Method requirements and assumptions

11.7 APPLICATIONS AND CASE STUDIES

11.7.1 Tectonic exhumation of normal fault footwalls

11.7.2 Paleotopography

11.7.3 Orogen-scale trends in thermochronologic dates

11.7.4 Detrital double-dating and sediment provenance

11.7.5 Volcanic double-dating, precise eruption dates, and magmatic residence times

11.7.6 Radiation-damage-and-annealing model applied to apatite

11.8 CONCLUSIONS

11.9 REFERENCES

Chapter 12 Uranium-series geochronology

12.1 INTRODUCTION

12.2 THEORY AND FUNDAMENTALS

12.2.1 The mathematics of decay chains

12.2.2 Mechanisms of producing disequilibrium

12.3 METHODS AND ANALYTICAL TECHNIQUES

12.3.1 Analytical techniques

12.4 APPLICATIONS

12.4.1 U-series dating of carbonates

12.4.2 U-series dating in silicate rocks

12.5 SUMMARY

12.6 REFERENCES

Chapter 13 Cosmogenic nuclides

13.1 INTRODUCTION

13.2 HISTORY

13.3 THEORY, FUNDAMENTALS, AND SYSTEMATICS

13.3.1 Cosmic rays

13.3.2 Distribution of cosmic rays on Earth

13.3.3 What makes a cosmogenic nuclide detectable and useful?

13.3.4 Types of cosmic-ray reactions

13.3.5 Cosmic-ray attenuation

13.3.6 Calibrating cosmogenic nuclide-production rates in rocks

13.4 APPLICATIONS

13.4.1 Types of cosmogenic nuclide applications

13.4.2 Extraterrestrial cosmogenic nuclides

13.4.3 Meteoric cosmogenic nuclides

13.5 CONCLUSION

13.6 REFERENCES

Chapter 14 Extinct radionuclide chronology

14.1 INTRODUCTION

14.2 HISTORY

14.3 SYSTEMATICS AND APPLICATIONS

14.3.1 26Al–26Mg

14.3.2 53Mn–53Cr chronometry

14.3.3 107Pd–107Ag

14.3.4 182Hf–182W

14.3.5 I–Pu–Xe

14.3.6 146Sm–142Nd

14.4 CONCLUSIONS

14.5 REFERENCES

Index

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