Porous Materials :Processing and Applications

Publication subTitle :Processing and Applications

Author: Liu   Peisheng;Chen   Guo-Feng  

Publisher: Elsevier Science‎

Publication year: 2014

E-ISBN: 9780124078376

P-ISBN(Paperback): 9780124077881

P-ISBN(Hardback):  9780124077881

Subject: TB383 Keywords special structure material

Language: ENG

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Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Description

Engineers and scientists alike will find this book to be an excellent introduction to the topic of porous materials, in particular the three main groups of porous materials: porous metals, porous ceramics, and polymer foams. Beginning with a general introduction to porous materials, the next six chapters focus on the processing and applications of each of the three main materials groups. The book includes such new processes as gel-casting and freeze-drying for porous ceramics and self-propagating high temperature synthesis (SHS) for porous metals. The applications discussed are relevant to a wide number of fields and industries, including aerospace, energy, transportation, construction, electronics, biomedical and others. The book concludes with a chapter on characterization methods for some basic parameters of porous materials. Porous Materials: Processing and Applications is an excellent resource for academic and industrial researchers in porous materials, as well as for upper-level undergraduate and graduate students in materials science and engineering, physics, chemistry, mechanics, metallurgy, and related specialties.

  • A comprehensive overview of processing and applications of porous materials – provides younger researchers, engineers and students with the best introduction to this class of materials
  • Includes three full chapters on modern applications - one for each of the three main groups of porous materials
  • Introduces readers to several c

Chapter

1.4.2. Characteristics of Porous Ceramics

1.5. Polymer Foams

1.5.1. Classifying Polymer Foams

1.5.2. Characteristics of Polymer Foams

Low Relative Density

Excellent Performance of Heat Insulation

Good Impact Energy Absorption

Excellent Sound Insulation

Great Specific Strength

1.6. Conclusions

References

Chapter Two: Making Porous Metals

2.1. Powder Metallurgy

2.1.1. Preparation of Metal Powders

Atomization

Mechanical Crushing

Reduction

Vapor Phase Deposition

Liquid Phase Deposition

Spherization of Powder

2.1.2. Molding of the Porous Body

Press Molding

Isostatic Pressing

Rolling of Powders

Plastification Extruding

Slurry Pouring

2.1.3. Sintering of the Porous Body

Migration Mechanism During Sintering

Influential Factors in Sintering

Features of Porous Material Sintering

Sintering Methods for Porous Materials

Sintering Process

Preparation of Materials with High Porosity

Examples

Common Porous Filter Metallic Materials

2.2. Fiber Sintering

2.2.1. Preparation of Metal Fibers

Cold Drawing

Spinning Method

Grinding

Plated Metal Sintering

Other Methods

2.2.2. Preparation of Porous Bodies

2.2.3. Electrode Plate with Porous Metal Fibers

2.3. Metallic Melt Foaming

2.3.1. Preparation of Porous Bodies

2.3.2. Technical Problems and Solutions

2.3.3. Case Studies on Porous Aluminum Preparation

2.4. Gas Injection into the Metallic Melt

2.5. Infiltration Casting

2.6. Metal Deposition

2.6.1. Vapor Deposition

Vacuum Vapor Deposition

Ambient Vapor Deposition

2.6.2. Electrodeposition

Principle and Processing

Ni Foam Preparation

Cu Foam Preparation

2.6.3. Reaction Deposition

2.7. Hollow Ball Sintering

2.7.1. Preparation of Hollow Balls

Slurry Method

Atomization

2.7.2. Preparation of Porous Bodies

2.7.3. Fe-cr Alloy Porous Products

2.8. Preparation of the Directional Porous Metal

2.8.1. Solid-Gas Eutectic Solidification

2.8.2. Directional Solidification

2.9. Other Methods

2.9.1. Powder Melting Foaming

2.9.2. Investment Casting

2.9.3. Self-Propagating, High-Temperature Synthesis (SHS)

2.10. Preparation of Porous Metal Composites

2.11. Special Processing of Porous Metals

Numerical Control (NC) Electric Spark Cutting

Water Jet Processing

Laser Processing

2.12. Concluding Remarks

References

Chapter Three: Application of Porous Metals

3.1. Introduction

3.1.1. Functional Applications

3.1.2. Structural Applications

3.2. Filtation and Separation

3.2.1. Industrial Filtration

3.2.2. Gas Purification

3.3. Sound Absorption

3.3.1. Sound Absorption Mechanism of Metal Foams

3.3.2. Influence Factor of Sound Absorption

Airflow Resistance

Incidence Wave Frequency

Porosity and Pore Size

Thickness of Porous Body

Influence of Back Cavity

Temperature and Humidity

3.3.3. Metal Foam with Improved Sound Absorption

Gradient Pore Structured Metal Foams

Other Issues

3.3.4. Applications

3.3.5. the Model for Calculation of Sound Absorption Coefficient

3.4. Heat Exchange

3.4.1. Heat Exchanger

3.4.2. Heat Radiator

3.4.3. Heat Tube

3.4.4. Resistance Heater

3.4.5. Composite Phase Transformation Materials

3.4.6. Cooling Materials

3.5. Porous Electrode

3.5.1. Nickel Foam

3.5.2. Pb Foam

3.5.3. Fuel Cell

3.6. Application in Transportation

3.6.1. Light Structure

3.6.2. Absorption of Impact Energy

3.6.3. Noise Control

3.6.4. Other Options

3.7. Applications in Biology and Iatrology

3.7.1. Applicability of Materials

3.7.2. Mechanical Requirements

3.7.3. Ti Foam

3.7.4. Ta and Stainless Steel Foams

Ta Foam

Stainless Steel Foams

3.7.5. Gradient Structure and Composite

3.7.6. Mechanism of Bone Formation

3.8. Other Applications

3.8.1. Energy Absorption and Vibration Control

General Application

Magnetorheological Fluid Damper

3.8.2. Electromagnetic Shielding

3.8.3. Fighting Flames

3.8.4. Mechanical Parts

3.8.5. Building Materials

3.8.6. Catalytic Reactions

3.9. Some Application Illustrations for Refractory Metal Porous Products

3.9.1. W Foam

3.9.2. Ta Foam

3.9.3. Mo Foam

3.10. Concluding Remarks

References

Chapter Four: Special Porous Metals

4.1. Amorphous Metal Foams (AMFs)

4.2. Gradient Porous Metals

4.3. Porous Metallic Lattice Materials

4.4. Nanoporous Metal Foams (NMFs)

Preparation Methods

Three-dimensional NMFs

Application Examples of NMF

Porous Gold

Nanoporous AMFs

4.5. Porous Metallic Films and Thin Films Carried on Metal Foams

4.5.1. Porous Metallic Films

4.5.2. Thin Films Carried on Metal Foam

4.6. Conclusions

References

Chapter Five: Fabricating Porous Ceramics

5.1. Particle Stacking Sintering

5.2. Appending Pore-forming Agent

5.2.1. Addition of Pore-forming Material in Powders

5.2.2. Slurry with Pore-Forming Agent

5.3. Polymeric Sponge Impregnation Process

5.3.1. the Selection of Organic Foam and the Pretreatment

5.3.2. Ceramic Slurry Preparation and Impregnating

Selection of Ceramic Powders

Slurry Preparation

Slurry Impregnating

5.3.3. Drying and Sintering of Green Bodies

5.3.4. Progress of Organic Foam Impregnating in Slurry

5.3.5. the Obtainment of the Ceramic Foam with High Strength

Two-time Coating of Slurry

Siliconizing Process

Toughening in the Second Phase

Modification of the Sintering Process

5.4. Foaming Process

5.4.1. Green Body Foaming

5.4.2. Slurry Foaming

Technical Principle

Formation of Pores

Foaming Agent System

Inorganic Foaming Agents

Organic Foaming Agents

Surfactant

Technological Application Development

Effect of the pH Value of Slurry

5.4.3. Evaluation of the Processing

5.5. Sol-gel Method

5.5.1. Different Templates

Template of the Stacking with Uniform Particles

Template of Organic Foam

5.5.2. Example of Preparation of Porous Ceramics

Preparation of Porous Alumina

Preparation of Porous SiO2 and Permutite

5.6. New Processing of Porous Ceramics

5.6.1. Gel Casting

5.6.2. Wood Ceramics

5.6.3. Freeze-Drying Method

5.6.4. Self-propagating High-Temperature Synthesis (SHS)

5.6.5. Hollow-Sphere Sintering

5.6.6. Other Processes

Foam Precursor Reaction

Stacking of Organic Foam Particles

Phase Separation

5.7. the Preparation of New Types of Porous Ceramic

5.7.1. Hydrophobic Porous Ceramics

5.7.2. Ceramic Foam with Gradient Pores

5.7.3. Fiber-porous Ceramics

5.7.4. Slender Porous Ceramic Tubes

5.7.5. Porous Ceramics with Directionally Arrayed Pores

5.7.6. Porous Ceramic Powder

5.8. Preparation of Porous Ceramic Membranes

5.8.1. Sol-gel

5.8.2. Other Methods

5.8.3. Preparation Examples for Porous Ceramic Membranes

5.8.4. A Porous TiO2 Film with Submicropores

Preparation of Dense TiO2 Film

Preparation of Porous TiO2 Film

Formation Mechanism of the Pore Structure in TiO2 Film

5.9. Porous Ceramic Composites

5.10. Ceramic Honeycombs

5.11. Concluding Remarks

References

Chapter Six: Applications of Porous Ceramics

6.1. Filtration and Separation

6.1.1. Filtration of Molten Metals

Filtration of Al Alloys

Filtration of Cu Alloys

Filtration for Casting of Irons and Steels

Filtration in the Automobile Industry

6.1.2. Hot Gas Filtration

6.1.3. Microfiltration

6.1.4. Fluid Separation

Separation of Mixed Gases

Separation of Nonmixed Fluids

Separation of Fluid with Microparticles

6.1.5. Parameters of Separation and Filtration

6.2. Functional Materials

6.2.1. Biological Materials

6.2.2. Ecomaterials (Environmental Materials)

6.2.3. Heat Insulation and Exchange

Heat Insulation Materials

Heat Exchange

6.2.4. Sound Absorption and Damping

Sound Absorption Materials

An Introduction of a Porous Oxide Composite

The Sound Absobility for the Porous Oxide Composite

Comparison in Sound Absorbability

Comparison with Glass Wool

Comparison with Polyester Fiber Wool

Comparison with Dow Polythene Foam

Damping Materials

6.2.5. Sensors (Sensing Elements)

6.3. Chemical Engineering

6.3.1. Catalyst Carriers

6.3.2. Porous Electrodes and Membranes

Porous Electrodes

Porous Membranes

Porous Photocatalytic Film of Titanium Dioxide

6.3.3. Ion Exchange and Desiccants

Ion Exchange

Desiccant

6.3.4. Gas Introduction

6.4. Combustion and Fire Retardance

6.4.1. Combustor

6.4.2. Flame Arrester

6.5. Overall Comments on the Application of Porous Ceramics

6.6. Concluding Remarks

References

Chapter Seven: Producing Polymer Foams

7.1. the Foaming Mechanism of Plastic Foam

7.1.1. Raw Materials

High Polymers

Fillers

Assistants

7.1.2. Foaming Methods

Physical Foaming

Chemical Foaming

Mechanical Foaming

7.1.3. Formation of Bubble Nuclei

The Free Space in the High-Polymer Molecule as the Nucleation Site

The Low-Potential-Energy Site in the High-polymer Melt as the Nucleation Site

Direct Formation of Bubble Nuclei in a Mixture of Gas and Liquid

7.1.4. Growth of Bubbles

7.1.5. Stabilization and Solidification of the Foamed Body

Solidification of Thermoplastics

Solidification of the Thermoset Foam

7.1.6. the Foaming of Some Plastics

Cross-linking Foamed Body

Structural Foamed Body

Combined Foamed Body

7.2. Molding Process for Polymer Foams

7.2.1. Extrusion Foaming

Working Mechanism

Major Parameters

7.2.2. Injection Molding

Principles of Injection Molding

Main Parameters

7.2.3. Pour Foaming

7.2.4. Mold Pressing

7.2.5. Reaction Injection Molding (RIM)

7.2.6. Rotation Foaming

7.2.7. Hollow Blowing

7.2.8. Microwave Sintering

7.3. Flame-retardant Polymer Foam

7.3.1. Anti-flaming

7.3.2. Common Flame-Retarding Plastic Foams

Rigid PU Foamed Plastic

PE Foam

PE Foam

Composite Foam

7.4. Progress of Plastic Foam Preparation

7.4.1. Modification of Traditional Foamed Plastics

7.4.2. Microcellular Plastics

7.4.3. Sound-Absorbing Plastic Foams

7.4.4. Biodegradable Foamed Plastics

7.4.5. Reinforced Foamed Plastic

7.4.6. Posttreatment of Foamed Plastics

7.4.7. Plant Oil-based Plastic Foams

7.4.8. PU Plastic Foam

Zero ODP or Low-ODP Foaming Agents

Foaming with Changing Pressure

Assistant Foaming Agents

Utilization of Natural Resources

7.5. Concluding Remarks

References

Chapter Eight: Applications of Polymer Foams

8.1. Thermal Insulation Materials

8.1.1. Factors Affecting Thermal Insulation Performance

8.1.2. Thermal Insulation and Energy Saving Construction

8.2. Packaging Materials

8.3. Sound-Absorbing Materials

8.3.1. Product Features

8.3.2. Sound Absorption Principles and Mechanisms

8.3.3. PU Foam

8.4. Separation and Enrichment

8.4.1. Working Principles

8.4.2. Modification Application

8.4.3. Enrichment of Organic Poisonous Matters

8.5. Other Applications

8.5.1. Dust Arrestment

8.5.2. Structural Materials

8.5.3. Fireproofing Technology and Active Explosion Suppression

8.5.4. Buoyancy

8.6. Applications of Typical Kinds of Polymer Foam

8.6.1. Thermosetting Polymer Foams

8.6.2. Thermoplastic General Polymer Foams

8.6.3. Engineering Thermoplastic Foams

8.6.4. High-Temperature-Resistant Polymer Foams (Using Temperatures Higher Than 200c)

8.6.5. Functional Polymer Foams

8.6.6. Other Polymer Foams

8.7. New, Functional Polymer Foams

8.7.1. Microcellular Plastics

8.7.2. Magnetic Polymer Foams

8.7.3. Porous, Self-lubricating Plastics

8.8. Overall Application Review of Polymer Foams

8.9. Conclusions

References

Chapter Nine: Characterization Methods: Basic Factors

9.1. Porosity

9.1.1. Basic Mathematical Relationship

9.1.2. Microscopic Analysis

9.1.3. Mass-volume Direct Calculation

9.1.4. Soaking Medium

9.1.5. Vacuum Dipping

9.1.6. Floating

9.2. Pore Size

9.2.1. Microscopic Analysis

9.2.2. Bubble Method

Fundamental Principle

Testing and Equipment

Average Pore Size with Medium Flow

Evaluation

9.2.3. Penetrant Method

9.2.4. Gas Permeation

Fundamentals

Testing Methods

9.2.5. Liquid-liquid Method

Fundamentals

Case Study

9.2.6. Gas Adsorption

Fundamentals

Test Equipment and Methods

Evaluation

9.3. Pore Morphology

9.3.1. Microobservation Method

9.3.2. X-ray Tomography

Fundamentals

X-ray Photography

X-ray Tomography

Experimental Devices

X-ray Tomography with Medium Resolution

X-ray Tomography with High Resolution

Experimental Equipment

Reconfiguration Method

Image Feature

Example

9.3.3. Potential Examination by DC of Pore Defects

9.3.4. Other Methods

9.4. Specific Surface Area

9.4.1. Gas Adsorption Method (BET Method)

Fundamentals

Testing Method and Equipment

Static Method

Volume Method

Weight Method

Dynamic Method

Single-Point and Multipoint Methods

Adsorbate

9.4.2. Fluid Penetrant Method

9.5. Mercury Intrusion Method

9.5.1. Principle of Mercury Intrusion

9.5.2. Measurement of Pore Size and Distribution

9.5.3. Measurement of Specific Surface Area

9.5.4. Measurement of Apparent Density and Porosity

9.5.5. Experimental Instrument for Mercury Intrusion

9.5.6. Measurement Error Analysis and Treatment

Compressibility of Mercury

Contact Angle of Mercury to Porous Materials

Surface Tension of Mercury

Residual Air

Necking Pores

Dynamic Hysteresis Effect

Compressibility of the Sample

9.5.7. Scope of Application

Sample Type

Pressure and the Limit of Pore Size

9.5.8. Comparison of the Different Methods [7]

9.6. Concluding Remarks

References

Chapter Ten: Characterization Methods: Physical Properties

10.1. Sound Absorption Coefficient

10.1.1. Characterization of Sound Absorbability

10.1.2. Measurement of the Sound Absorption Coefficient

Standing Wave Ratio

Reverberation Chamber

Transfer Function

Testing of the Sound Absorbability of Metal Foams at High Temperatures

10.1.3. Analysis and Discussion

The Mechanism of Acoustic Attenuation [5]

Sound Absorption Influencing Factors

Relationship Between Sound Absorption and Frequency

10.2. Thermal Conductivity

10.2.1. Characterization of Thermal Conductivity and Diffusivity

10.2.2. Measurement of Thermal Conductivity

Steady Measurement

Direct Method

Comparison Method

Dynamic Measurement

10.2.3. Measurement of Thermal Conductivity for Porous Materials

Steady-state Planar Measurement (Steady-state Planar Heat Source Method)

Effective Thermal Conductivity and Contact Resistance of Porous Materials

Examples

10.2.4. Evaluation of Performance

The Influencing Factors of the Thermal Conductivity of Materials

The Influencing Factors of the Thermal Conductivity of Porous Materials

10.3. Electrical Resistivity/electrical Conductivity

10.3.1. Four-Probe Method

10.3.2. Double Bridge Method

10.3.3. Potentiometer Method

10.3.4. Eddy Method

10.4. Concluding Remarks

References

Index

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