R.B. Woodward Remembered :A Collection of Papers in Honour of Robert Burns Woodward 1917-1979 ( Tetrahedron Supplements )

Publication subTitle :A Collection of Papers in Honour of Robert Burns Woodward 1917-1979

Publication series :Tetrahedron Supplements

Author: Barton   D. H. R.  

Publisher: Elsevier Science‎

Publication year: 2013

E-ISBN: 9781483286082

P-ISBN(Paperback): 9780080292380

P-ISBN(Hardback):  9780080292380

Subject: O62 Organic Chemistry

Language: ENG

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Description

R.B. Woodward, Professor of Science at Harvard University, who died in July 1979, was generally considered to be the greatest organic chemist of modern times. He was one of the founders of Tetrahedron and Tetrahedron Letters and this volume, containing papers from over 50 of the world's leading organic chemists, is dedicated to his memory. The contents cover all areas of modern organic chemistry and therefore present a synopsis of current research in this area of science.

Chapter

CHAPTER 1. STEREOSPECIFIC SYNTHESIS OF METHYL 2,6-DIACETAMIDO-293,6-TRIDEOXY-α-D-RIBOHEXOFURANOSIDE AND HEXOPYRANOSIDE, DERIVATIVES OF TOBROSAMINE

EXPERIMENTAL

REFERENCES

CHAPTER 2. THE CHEMISTRY OF AN ALLYLSILANE: THE SYNTHESIS OF A PROSTAGLANDIN INTERMEDIATE AND OF LOGANIN†

THE GENERAL CHEMISTRY OF THE ALLYLSILANE (6)

THE SYNTHESIS OF THE PROSTAGLANDIN INTERMEDIATE (29)

THE SYNTHESIS OF LOGANIN

EXPERIMENTAL

REFERENCES

CHAPTER 3. CARBON-ALKYLATION OF SIMPLE NITRONATE ANIONS BY N-SUBSTITUTED PYRIDINIUMS

EXPERIMENTAL

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CHAPTER 4. REACTIONS DE PROXIMITE: ACYLATIO NINTRACOMPLEXE ENTRE UN ALCOOL ET UN ANHYDRIDE MIXTE COORDINES AU PLATINE(II)

RESULTATS ET DISCUSSION

PARTIE EXPERIMENTALE

BIBLIOGRAPHIE

CHAPTER 6. PROPRIETES CHIMIQUES DES α-HYDROXYNITRONES CYCLIQUES: ACTION DU BOROHYDRURE DE SODIUM, DU CHLORURE DE BENZOYLE ET DE p-TOLUENE SULFONYLE. SYNTHESE PARTIELLE DE DERIVESDU PREGNANE FONCTIONNALISES SUR LE CARBONE-18

PARTIE EXPERIMENTALE

BIBLIOGRAPHIE

CHAPTER 7. THERMAL REARRANGEMENTS OF TRICYCLO [4.2.2.02 5 JDECATRIENE DERIVATIVES

DISCUSSION

REFERENCES

CHAPTER 8. SYNTHESE TOTALE DES C-NOR D-HOMOSTEROIDES†—III‡

CONCLUSION

PARTIE EXPERIMENTALE

BIBLIOGRAPHIE

CHAPTER 9. FUNCTIONAL GROUP OXIDATION BY PENTAVALENT ORGANOBISMUTH REAGENTS†

EXPERIMENTAL

REFERENCES

CHAPTER 10. THE STRUCTURE OF FACTOR III

EXPERIMENTAL

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CHAPTER 11. THE STRUCTURE OF ACUMYCIN

EXPERIMENTAL

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CHAPTER 12. SYNTHESIS AND REACTIONS OF 5,6,11,12-TETRADEHYDRODIBENZO[α,e JCYCLOOCTENE AND 5,6-DIDEHYDRODIBENZO[α,e]CYCLOOCTENE†1,2

SYNTHESIS AND REACTIONS OF 5,6,11,12-TETRADEHYDRODIBENZO [α,eJCYCLOOCTENE (5)

SYNTHESIS AND REACTIONS OF 5,6-DIDEHYDRODIBENZO[α,t-]CYCLOOCTENE (6)

SPECTRAL AND OTHER PROPERTIES OF 5,6,11,12-TETRADEHYDRODIBENZO[α,e]CYCLOOCTENE (5) and 5,6-DIDEHYDRODIBENZO|α,e]CYCLOOCTENE (6)

CHEMICAL AND ELECTROCHEMICAL REDUCTIONS OF 5,6,ll,12-TETRADEHYDRODIBENZO[α,e]CYCLOOCTENE(5) AND 5,6-DIDEHYDRODIBENZO[α,e]CYCLOOCTENE (6)

EXPERIMENTAL

REFERENCES

CHAPTER 13. CAPTO-DATIVE SUBSTITUENT EFFECTS—VIII1

EXPERIMENTAL

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CHAPTER 14. APPROACHES TO THE SYNTHESIS OF TRITERPENOIDS—VIPa"c

EXPERIMENTAL

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CHAPTER 15. DI-π-METHANE HYPERSURFACES AND REACTIVITY;MULTIPLICITY AND REGIOSELECTIVITY; RELATIONSHIP BETWEEN THE DI-π-METHANE AND BICYCLE REARRANGEMENTS

EXPERIMENTAL40

REFERENCES

CHAPTER 16. THE STEREOCHEMISTRY OF 2-t-BUTYL-2-CYANO-3-PHENYLCYCLOBUTANONE BY COMPLETE ANALYSIS OF ITS 1H NMR SPECTRUM

DISCUSSION OF THE RESULTS

EXPERIMENTAL

REFERENCES

CHAPTER 17. SYNTHESIS OF THE O-ANTIGENIC POLYSACCHARIDE OF SALMONELLA NEWINGTON AND OF ITS ANALOGUE DIFFERING IN CONFIGURATION AT THE ONLY GLYCOSIDIC CENTRE

CONCLUSION

EXPERIMENTAL

REFERENCES

CHAPTER 18. A NEW SYNTHETIC ROUTE TO ( ± ) LYSERGIC ACID1

EXPERIMENTAL

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CHAPTER 19. STEREOCHEMISTRY OF MACROLIDES—IV1

EXPERIMENTAL

REFERENCES

CHAPTER 20. DIVALENT LANTHANIDE DERIVATIVES IN ORGANIC SYNTHESIS—II

INTRODUCTION

DISCUSSION

CONCLUSION

EXPERIMENTAL SECTION

REFERENCES

CHAPTER 21. OPTICAL ROTATORY DISPERSION STUDIES—131

RESULTS AND DISCUSSION

CONCLUSION

EXPERIMENTAL

REFERENCES

CHAPTER 22. THE DYE-SENSITIZED PHOTOOXIDATION OF IMIDAZOLES

EXPERIMENTAL

REFERENCES

CHAPTER 23. BIOSYNTHESIS OF PSEUROTIN A

CONCLUSIONS

EXPERIMENTAL

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CHAPTER 24. DIARYL TELLUROXIDES AS NEW MILD OXIDISING REAGENTS†

EXPERIMENTAL

REFERENCES

CHAPTER 25. REACTIONS OF STEROIDAL 1,3-DIKETONES WITH SULFUR TETRAFLUORIDE†

EXPERIMENTAL ‡

REFERENCES

CHAPTER 26. THE METABOLITES OF THE MARINE MOLLUSCS TRIDACHIELLA DIOMEDEA AND TRIDACHIA CRISP ATA

EXPERIMENTAL

REFERENCES

CHAPTER 27. SYNTHESES IN THE ELLIPTICINE-OLIVACINE SERIES

EXPERIMENTAL

REFERENCES

CHAPTER 28. CATIONIC π-CYCLISATION OF α,β-UNSATURATED CARBONYL COMPOUNDS

EXPERIMENTAL

REFERENCES

CHAPTER 29. EPIMERIZATION AT A QUATERNARY C-SUBSTITUTED CARBON ATOM

EXPERIMENTAL

REFERENCES

CHAPTER 30. PHENYLSELENYLATION OF ARACHIDONIC ACID AS A ROUTE TO INTERMEDIATES FOR LEUKOTRIENE SYNTHESIS

RESULTS AND DISCUSSION

EXPERIMENTAL

REFERENCES

CHAPTER 31. SYNTHETIC APPROACHES TO POLYHYDROXYAGAROFURANS†

EXPERIMENTAL

REFERENCES

CHAPTER 32. IZUMENOLIDE—A NOVEL β-LACTAMASE INHIBITOR PRODUCED BY MICROMONOSPORA—III

RESULTS AND DISCUSSION

REFERENCES

CHAPTER 33. STEREOCONTROLLED PREPARATION OF PRECURSORS TO ALL PRIMARY PROSTAGLANDINS FROM BUTADIENE!

EXPERIMENTAL

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CHAPTER 34. ORGANOMETALLIC COMPOUNDS IN ORGANIC SYNTHESIS—XI

STRATEGIES OF ORGANIC SYNTHESIS

EXPERIMENTAL

REFERENCES

CHAPTER 35. SYNTHESIS OF ISOPRENOID NATURAL PRODUCTS FROM β-KETO ESTERS

EXPERIMENTAL

REFERENCES

CHAPTER 36. TOTAL SYNTHESIS OF APHIDICOLIN

EXPERIMENTAL

REFERENCES

CHAPTER 37. CONSTITUTIONAL AND CONFIGURATIONAL ASPECTS OF THE THERMAL REORGANIZATION OF l-CYANO-2-VINYLCYCLOBUTANE (I)

EXPERIMENTAL

REFERENCES

CHAPTER 38. AB INITIO ELECTRON DENSITY ANALYSIS OF â-.FLUOROETHYL ANION: THE NON-IMPORTANCE OF ANIONIC FLUORINE HYPERCONJUGATION†

SUMMARY

REFERENCES

CHAPTER 39. A LOGIC FOR SYNTHESIS DESIGN1

CONCLUSION

REFERENCES

CHAPTER 40. TOTAL SYNTHESIS OF PSEUDOGUAIANOLIDES—II

EXPERIMENTAL 22

REFERENCES

CHAPTER 41. THE STERPURIC ACIDS

EXPERIMENTAL

REFERENCES

CHAPTER 42. REGIO-CONTROLLED SYNTHESIS OF SUBSTITUTED PHENOLS1

EXPERIMENTAL

REFERENCES

CHAPTER 43. SUBSTITUTION NUCLEOPHILE AROMATIQUE RADICALAIRE.1 NOUVELLE SYNTHÉSE DU SQUELETTE INDOLE

RESULTATS

DISCUSSION

CONCLUSION

PARTIE EXPERIMENTALE

REFERENCES

CHAPTER 44. PARTIAL SYNTHESIS OF CHLOROPHYLL-A FROM RHODOCHLORIN

EXPERIMENTAL

REFERENCES

CHAPTER 45. CHARACTERIZATION OF THE HYDROPEROXIDES DERIVED FROM SINGLET OXYGEN OXIDATION OF ( + )-LIMONENE

EXPERIMENTAL

REFERENCES

CHAPTER 46. SYNTHESES OF PGF2α AND CLOPROSTENOL

EXPERIMENTAL

REFERENCES

CHAPTER 47. MOLECULAR STRUCTURE AND TAUTOMERISM OF THE 1,3,2-BENZODIOXAARSOLE ETHER OF TROPOLONE

EXPERIMENTAL

REFERENCES

CHAPTER 48. A CONVENIENT SYNTHESIS OF α-AMINO-β-LACTAMS1,α

CONCLUSIONS

EXPERIMENTAL

REFERENCES

CHAPTER 49. TOTAL SYNTHESIS OF GLIOTOXIN, DEHYDROGLIOTOXIN AND HYALODENDRIN†

EPIDITHIAPIPERAZINEDIONE SYNTHESES: METHOD A (BICYCLIC ROUTE)

TOTAL SYNTHESIS OF GLIOTOXIN

EXPERIMENTAL

REFERENCES

CHAPTER 50. THE CORAXENIOLIDES, CONSTITUENTS OF PINK CORAL, CORALLIUM SP.1α

EXPERIMENTAL

REFERENCES

CHAPTER 51. STERIC MODE OF ENZYMIC HYDROXYLATION AT PRIMARY CARBON ATOMSα

EXPERIMENTAL

REFERENCES

CHAPTER 52. INTRAMOLECULAR CYCLOADDITIONS OF NITRONES JOINED BY AMIDES TO OLEFINS

INTRODUCTION

STARTING MATERIALS

DISCUSSION

EXPERIMENTAL

REFERENCES

CHAPTER 53. A CHEMICAL AND THERMOCHEMICAL STUDY OF NON-OBSERVED SYMMETRY ALLOWED REACTIONS†

EXPERIMENTAL

REFERENCES

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