Diaqua­bis(1,2‐di‐4‐pyridylethane‐κN)bis­(2‐nitro­benzoate‐κO)manganese(II)

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|63|1|m235-m237

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.63, Iss.1, 2007-01, pp. : m235-m237

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Abstract

In the title mixed‐ligand complex, [Mn(C7H4NO4)2(C12H12N2)2(H2O)2], was synthesized and its crystal structure was studied. The Mn atom is six‐coordinated in slightly distorted octa­hedral coordination geometry by two N atoms of two 1,2‐di‐4‐pyridylethane ligands (L), two O atoms of monodentate 2‐nitro­benzoate ligands and two O atoms of water mol­ecules. The Mn atom is located on a centre of inversion. A one‐dimensional structure is formed in the [101] direction by inter­molecular hydrogen bonds between the aqua ligands and N atoms of L. An intra­molecular hydrogen bond between the other aqua ligand and a neighbouring O atom of a carboxyl­ate group is also observed.