Stoichiometric ZrGeTe4

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|63|10|i183-i183

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.63, Iss.10, 2007-10, pp. : i183-i183

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Abstract

Zirconium germanium tetratelluride, ZrGeTe4, is isostructural with Hf0.85GeTe4 [Mar Ibers (1993). J. Am Chem. Soc.115, 3227–3238], but the Zr site in ZrGeTe4 is fully occupied and the compound is stoichiometric. ZrGeTe4 adopts a layered structural type. Each layer is composed of two unique one‐dimensional chains of face‐sharing Zr‐centered bicapped trigonal prisms and corner‐sharing Ge‐centered tetrahedra.