(2‐Methacrylato)[tris(1‐methyl‐1H‐benzimidazol‐2‐ylmethyl)amine]copper(II) perchlorate dimethylformamide disolvate hemihydrate at 153 (2) K

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|63|10|m2576-m2576

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.63, Iss.10, 2007-10, pp. : m2576-m2576

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

In the title complex, [Cu(C4H5O2)(C27H27N7)](ClO4)·2C3H7NO·0.5H2O, the CuII ion is five‐coordinated by four N atoms from a tris(N‐methylbenzimidazol‐2‐ylmethyl)amine ligand and one O atom from a 2‐methacrylate ligand in a distorted trigonal–bipyramidal geometry with approximate molecular C3 symmetry. A half‐occupancy solvent water molecule forms weak O—H...O hydrogen bonds and the atoms of the 2‐methacrylate ligand are disordered over two sites with equal occupancy.