

Publisher: John Wiley & Sons Inc
E-ISSN: 1600-5368|63|10|m2576-m2576
ISSN: 1600-5368
Source: Acta Crystallographica Section E, Vol.63, Iss.10, 2007-10, pp. : m2576-m2576
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Abstract
In the title complex, [Cu(C4H5O2)(C27H27N7)](ClO4)·2C3H7NO·0.5H2O, the CuII ion is five‐coordinated by four N atoms from a tris(N‐methylbenzimidazol‐2‐ylmethyl)amine ligand and one O atom from a 2‐methacrylate ligand in a distorted trigonal–bipyramidal geometry with approximate molecular C3 symmetry. A half‐occupancy solvent water molecule forms weak O—H...O hydrogen bonds and the atoms of the 2‐methacrylate ligand are disordered over two sites with equal occupancy.
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