[Bis(1H‐benzimidazol‐2‐ylmethyl)amine‐κ3N,N′,N′′]dinitratolead(II)

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|63|7|m1792-m1792

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.63, Iss.7, 2007-07, pp. : m1792-m1792

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Abstract

In the title compound, [Pb(NO3)2(C16H15N5)], the PbII ion is chelated by three N atoms of a bis(1H‐benzimidazol‐2‐ylmethyl)amine (IDB) ligand and two O atoms from each of two nitrate ligands, resulting in an asymmetric seven‐coordinate configuration. The crystal structure is stabilized by intermolecular N—H...O and C—H...O hydrogen bonds and π–π interactions, with ring‐centroid separations of 3.578 (5) and 3.686 (5) Å, leading to a three‐dimensional network.