Di‐μ‐chloro‐bis­[chloro­(phenyl 2‐pyridyl ketone oxime‐κ2N,N′)copper(II)]

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|62|9|m2348-m2349

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.62, Iss.9, 2006-09, pp. : m2348-m2349

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Abstract

The title complex, [Cu2Cl4(C12H10N2O)2], was synthesized by reacting phenyl 2‐pyridyl ketone oxime with CuCl2·2H2O in a basic medium. The organic ligand coordinates to the CuII ions through its N atoms, while the oxime O atom remains uncoordinated. The Cl ions play two roles: one is a terminal ligand and the other is a bridging ligand, the bridge being formed through a crystallographic inversion centre.