μ‐Sulfato‐1κO:2κO‐μ‐oxo‐bis[tris(2‐pyridylmethyl)amine‐κ⁴N,N′,N′′,N′′′]diiron(III) diperchlorate acetonitrile/water (0.75/0.25) solvate

Publisher： John Wiley & Sons Inc

E-ISSN： 1600-5368|63|10|m2480-m2481

ISSN： 1600-5368

Source： Acta Crystallographica Section E, Vol.63, Iss.10, 2007-10, pp. : m2480-m2481

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Abstract

The title complex, [Fe₂(C₁₈H₁₈N₄)₂O(SO₄)](ClO₄)₂·0.75C₂H₃N·0.25H₂O, consists of two perchlorate ions, a solvent cavity with acetonitrile and water (disordered 3/1), and an Fe complex dication. The dication is a diiron(III) unit containing an oxo bridge and a sulfato bridge. The iron(III) centers are pseudo‐octahedral, six‐coordinate, with tris(2‐pyridylmethyl) amine (TPA) providing four N atoms. The distances and angles are typical for bent μ‐oxo‐bridged TPA complexes. The complex was the unexpected result of a reaction designed to produce a μ‐sulfido–μ‐carboxylato–diiron center.

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