Poly[[bis­(salicylato‐κO)copper(II)]‐di‐μ‐3‐pyridylmethanol‐κ2N:O;κ2O:N]: a redetermination at 100 K

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|62|12|m3385-m3387

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.62, Iss.12, 2006-12, pp. : m3385-m3387

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Abstract

The crystal structure of the polymeric title compound, [Cu(C7H5O3)2(C6H7NO)2]n, has been reported previously at room temperature by Hoang, Valach, Macášková Melník [Acta Cryst. (1992) C48, 1933–1936]. The centrosymmetric coordination environment of CuII at 100 K displays elongation of the Cu—N bonds and contraction of the Cu—O bonds to the 3‐pyridylmethanol ligands, compared with the room‐temperature structure. The Cu—O bond lengths to the carboxyl­ate groups of the salicylate ligands are comparable at both temperatures.