[η2‐8‐(tert‐Butyl­imino)‐1‐naphth­yl]bis­(η5‐cyclo­penta­dien­yl)titanium(IV)

Publisher： John Wiley & Sons Inc

E-ISSN： 1600-5368|62|7|m1545-m1547

ISSN： 1600-5368

Source： Acta Crystallographica Section E, Vol.62, Iss.7, 2006-07, pp. : m1545-m1547

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Abstract

The title compound, [Ti(C5H5)2(C15H15N)], displays an iminoacyl fragment in an N‐outside conformation, indicating that the C=N vector points away from the σ‐bonded C atom. Considering only the geometrical centres of all η‐coordinated groups, the TiIV ion adopts a severely distorted tetra­hedral configuration. The crystal packing displays a short C—H⋯π contact linking the mol­ecules into an infinite chain running along the b‐axis direction.

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