5-Furan-2yl[1,3,4]oxadiazole-2-thiol, 5-Furan-2yl-4H [1,2,4] triazole-3-thiol and Their Thiol-Thione Tautomerism

Author: Koparır M.   Çetin A.   Cansız A.  

Publisher: MDPI

E-ISSN: 1420-3049|10|2|475-480

ISSN: 1420-3049

Source: Molecules, Vol.10, Iss.2, 2005-02, pp. : 475-480

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Abstract

5-Furan-2-yl[1,3,4]oxadiazole-2-thiol (Ia) and 5-furan-2-yl-4H-[1,2,4]- triazole-3-thiol (Ib) were synthesized from furan-2-carboxylic acid hydrazide. Mannich bases and methyl derivatives were then prepared. The structures of the synthesized compounds were confirmed by elemental analyses, IR and 1H-NMR spectra. Their thiol-thione tautomeric equilibrium is described.