CH—Acids
：A Guide to All Existing Problems of CH-Acidity with New Experimental Methods and Data, Including Indirect Electrochemical, Kinetic and Thermodynamic Studies
Publication subTitle ：A Guide to All Existing Problems of CH-Acidity with New Experimental Methods and Data, Including Indirect Electrochemical, Kinetic and Thermodynamic Studies
Author： Reutov O. A.;Beletskaya I. P.;Butin K. P.
Publisher： Elsevier Science
Publication year： 2016
E-ISBN: 9781483163833
P-ISBN(Paperback): 9780080216102
Subject： O622.5 The organic carboxylic acid and its derivatives
Keyword： 化学
Language： ENG
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Description
Ch-Acids deals with the acidity of all organic compounds containing C-H bonds. CH-acidity characterizes thermodynamic stability of carbanions in a medium containing a proton donor as carbanion acceptor.
The book primarily explains proton transfer stereochemistry or structure in relation to CH-acidity patterns. Methods to study equilibrium acidity; tabulation of pKa values of CH-acids; and equilibrium acidity as a function of CH-acid structures are presented. Topics on kinetic CH-acidity; stereochemistry of proton transfer in CH-acids; and factors obscuring experimental observation of the action of the Bronsted equation are discussed extensively.
The text will be of importance to organometallic and organic chemists.