Library of Congress Cataloging-in-Publication Data

Contents

Preface

Introduction

1.1. Technological Applications of the Supercritical Fluid Mixtures Containing CO2

1.2. Technological Applications of the Supercritical Fluid Mixtures Containing H2O

1.3. Scientific Applications of the Supercritical Fluid Mixtures

The Critical Properties of Binary Mixtures and Related Thermodynamic Properties

2.1. The Critical Properties of Binary Mixtures and the Krichevskii Parameter

2.2. Partial Molar Volume, Henry’s Constant, Distribution Coefficient, Solubility, and Structurtal Properties of Dilute Mixtures and Krichevskii Parameter

2.3. The Critical Curves Shape Behavior and Asymptotic Scaling Properties of Binary Mixtures Near the Critical Points of Pure Solvent

Experimental Methods

3.1. Method-1. Observation of the Appearance and Disappearance of Meniscus at The Vapor-Liquid Interface. “Sealed Tube” Method

3.2. Method 2: Law of Rectilinear Diameter

3.3. Method 3: PVT Relations, ((P/(V)T = (( 2P/(V2)T =0

3.4. Method 4: Pulse Heating Method

3.5. Method 5: Flow Apparatus

3.6. Method 6: Acoustic Method of Determination of the Critical Points

3.7. Method 7: Method of Quasi-Static Thermograms

The Critical Properties of Binary CO2+Solute Mixtures

4.1. The Critical Properties of Binary CO2+Alcohol Mixtures

4.2. The Critical Properties of Binary CO2+N-Alkane Mixtures

4.3. The Critical Properties of Binary CO2+Aromatic Hydrocarbon Mixtures

4.4. The Critical Properties of Binary CO2+H2O Mixtures

4.5. The Critical Properties of Binary CO2+Monatomic Gas (He, Ar, Kr, And Xe) Mixtures

4.6. The Critical Properties of Binary CO2+Twoatomic Gases (O2, N2, H2 )

4.7. The Critical Properties of CO2+ Poly-Atomic Fluid (H2S, SO2, N2O, SF6, NH3) Mixtures

4.8. The Critical Properties of CO2+Refrigerant (CHF3, CH2F2, R134a) Mixtures

4.9. The Critical Properties of Binary CO2+(Ethylene, Acetylene, Cyclohexane, and Isomers)

4.10. The Critical Properties of Binary CO2+ (Pyridine, Ethanoic Acid, Acetone, Chloroform, Acetonitrile, And Tetrahydrofuran) Mixtures

The Critical Properties of Binary Aqueous Solutions

5.1. The Critical Properties of Binary Aqueous Salt Solutions

5.2. The Critical Properties of Binary Aqueous Alcohol Solutions

5.3. The Critical Properties of Binary Aqueous Gas Solutions

5.4. The Critical Properties of Binary Aqueous Hydrocarbon Solutions

5.5. The Critical Properties of H2O+D2O

Conclusion

Acknowledgments

References

Compilation of the Critical Properties of Binary Mixtures Containing Carbon Dioxide

Compilation of the Critical Properties of Binary Aqueous Solutions

Index