Solids Role in Tertiary Chemical Phosphorus Removal by Alum ( WERF Research Report Series )

Publication series :WERF Research Report Series

Author: J. B. Neethling  

Publisher: IWA Publishing‎

Publication year: 2014

E-ISBN: 9781780406763

Subject: X703.5 aid

Keyword: 工业技术

Language: ENG

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Solids Role in Tertiary Chemical Phosphorus Removal by Alum

Description

The need to control and remove phosphorus (P) in discharges from waste water treatment facilities (WWTF) to prevent eutrophication of receiving waters is well known. Regulatory initiatives are further contributing to the addition of stringent P limits to discharge permits. Accordingly, many agencies are facing increasingly stringent standards of effluent P and as a result the effluent limit of 0.1 mg P/L total phosphorus (TP) or lower is being achieved. Since the reliable performance limit of enhanced biological phosphorus removal (EBPR) is commonly accepted at about 0.1 mg P/L in the dissolved form, these facilities will need to utilize tertiary chemical phosphorus removal (CPR) to reliably achieve limits lower than 0.1 mg P/L (ultra-low limits) (Pagilla and Urgun-Demirtas, 2007).  


The mechanistic basis for P removal using chemical precipitant addition is generally considered to be more than simple precipitation. The role of adsorption and/or surface complexation in removal of reactive or unreactive phosphorus to the already formed chemical precipitates or complexes has been reported. Omoike and VanLoon (1999) showed that the most likely mechanism involves sorption of P species on Al(OH)3(s) formed by Al salt addition to water for P removal, and further precipitation/complexation of P onto the Al hydroxyl precipitate for additional P removal. In tertiary P removal, usually a non-stoichiometric dose or several times stoichiometric dose of the precipitan

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EXECUTIVE SUMMARY

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