Binary Polar Liquids :Structural and Dynamic Characterization Using Spectroscopic Methods

Publication subTitle :Structural and Dynamic Characterization Using Spectroscopic Methods

Author: Mehrotra   Suresh C.;Kumbharkhane   Ashok;Chaudhari   Ajay  

Publisher: Elsevier Science‎

Publication year: 2017

E-ISBN: 9780128132548

P-ISBN(Paperback): 9780128132531

Subject: O441.4 electromagnetic field and electromagnetic wave

Keyword: 化学原理和方法,化学

Language: ENG

Access to resources Favorite

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Description

Binary Polar Liquids: Structural and Dynamic Characterization Using Spectroscopic Methods provides liquid state physical chemists and physicists with practical theoretical models based on a wealth of robust data that describe the dielectric properties of dipolar materials in a systematic manner. In many applications, reference measurements using dielectric permittivity data are required.

Over the past three decades, the author has compiled and analyzed permittivity research data and relaxation times for various polar liquids and their mixtures. The resulting structural data - as determined from various models - is critically evaluated, arming scientists with a complete characterization of the spectra of water-containing mixtures.

  • Includes theoretical models that describe dielectric properties of dipolar materials
  • Features reference measurements using dielectric permittivity data
  • Describes the experimental techniques and procedures to extract the permittivity spectra and determination of different molecular parameters
  • Provides a critical evaluation and analysis of research data compiled and consolidated over more than 30 years

Chapter

1.3.5 The Frohlich Theory

1.4 DYNAMICAL THEORY OF DIELECTRICS

1.4.1 The Debye Model

1.4.2 The Cole–Cole Model

1.4.3 The Cole–Davidson Model

1.4.4 The Havriliak–Negami Model

1.4.5 The Double-Debye (Two-Debye) Model

1.5 DIELECTRIC MODELS RELATED TO MOLECULAR BEHAVIOR

1.5.1 Kirkwood Correlation Factor

1.5.2 Kirkwood Correlation Factor in Binary Mixture

1.5.3 Excess Dielectric Constant

1.5.4 The Modified Bruggeman Model

1.5.5 The Redlich–Kister Model23

1.6 THERMODYNAMIC PARAMETERS

1.7 EXPERIMENTAL TECHNIQUE

1.7.1 Dielectric Relaxation Spectroscopy

1.7.2 Basic Principle of TDR

1.7.3 Sampling Oscilloscope

1.7.4 Sample Cell

1.7.5 Choice of Time Window

1.8 DATA ANALYSIS

1.8.1 Bilinear Calibration Method

1.8.2 An Example: Determination of Relaxation Time and Distribution Parameters

1.9 CONCLUSION

References

2 - Dielectric Relaxation in Binary Polar Liquids Containing Alcohols and Molecules With –OH Group

2.1 INTRODUCTION

2.2 WATER–METHANOL BINARY SYSTEM

2.3 THE WATER–ETHANOL SYSTEM

2.4 THE WATER–PROPANOL SYSTEM

2.5 THE WATER–ETHYLENE GLYCOL SYSTEM

2.6 THE WATER–TERTIARY BUTYL ALCOHOL SYSTEM

2.7 THE ETHANOL–ETHYLENE GLYCOL SYSTEM

2.8 OTHER SIMILAR SYSTEM

2.9 CONCLUSION

References

3 - Spectroscopic Characterization of Binary Polar Liquid Mixtures Containing Amino or Sulfoxide Group and Hydroxyl ...

3.1 INTRODUCTION

3.2 N,N–DIMETHYLAMINOETHANOL–FORMAMIDE BINARY SYSTEM

3.3 WATER–FORMAMIDE BINARY SYSTEM

3.4 WATER–N-METHYLFORMAMIDE BINARY SYSTEM

3.5 WATER–N,N-DIMETHYLFORMAMIDE BINARY SYSTEM

3.6 2-ETHOXYETHANOL–N,N-DIMETHYLFORMAMIDE BINARY SYSTEM

3.7 ETHANOL–N,N-DIMETHYLFORMAMIDE BINARY SYSTEM

3.8 PROPANOL–N,N-DIMETHYLFORMAMIDE BINARY SYSTEM

3.9 ETHANOLAMINE–N,N-DIMETHYLACETAMIDE BINARY SYSTEM

3.10 WATER–DIMETHYLSULFOXIDE BINARY SYSTEM

3.11 ETHANOL–DIMETHYLSULFOXIDE BINARY SYSTEM

3.12 PROPANOL–DIMETHYLSULFOXIDE BINARY SYSTEM

3.13 2-ETHOXYETHANOL–DIMETHYLSULFOXIDE BINARY SYSTEM

3.14 ANILINE–DIMETHYLSULFOXIDE BINARY SYSTEM

3.15 ANILINE–METHANOL BINARY SYSTEM

3.16 ANILINE–ETHANOL BINARY SYSTEM

3.17 ANILINE–PROPANOL BINARY SYSTEM

3.18 ANILINE–BUTANOL BINARY SYSTEM

3.19 ANILINE–HEXANOL BINARY SYSTEM

3.20 ANILINE–HEPTANOL BINARY SYSTEM

3.21 ANILINE–N,N-DIMETHYLFORMAMIDE BINARY SYSTEM

3.22 OTHER SIMILAR SYSTEMS

3.23 CONCLUSIONS

References

4 - Structural Dynamics of Binary Mixture of Monohydroxyl Alcohol With Ester

4.1 INTRODUCTION

4.2 METHYL ACETATE–METHANOL BINARY SYSTEM

4.3 METHYL ACETATE–ETHANOL BINARY SYSTEM

4.4 METHYL ACETATE–1-PROPANOL BINARY SYSTEM

4.5 ETHYL ACETATE–METHANOL BINARY SYSTEM

4.6 ETHYL ACETATE–ETHANOL BINARY SYSTEM

4.7 ETHYL ACETATE–1-PROPANOL BINARY SYSTEM

4.8 N-BUTYL ACETATE–METHANOL BINARY SYSTEM

4.9 N-BUTYL ACETATE–ETHANOL BINARY SYSTEM

4.10 N-BUTYL ACETATE–1-PROPANOL BINARY SYSTEM

4.11 OTHER SIMILAR SYSTEMS

4.12 CONCLUSION

References

5 - Dielectric Spectroscopic Study of Molecular Interaction Between Nitriles With Water and Alcohol

5.1 INTRODUCTION

5.2 PURE NITRILES

5.3 ACETONITRILE–WATER BINARY SYSTEM

5.4 ACETONITRILE–METHANOL BINARY SYSTEM

5.5 BUTANENITRILE–METHANOL BINARY SYSTEM

5.6 PENTANENITRILE–METHANOL BINARY SYSTEM

5.7 HEXANENITRILE–METHANOL BINARY SYSTEM

5.8 OCTANENITRILE–METHANOL BINARY SYSTEM

5.9 P-FLUOROPHENYLACETONITRILE–METHANOL BINARY SYSTEM

5.10 OTHER SIMILAR SYSTEMS

5.11 CONCLUSIONS

References

6 - Molecular Interaction in Associating and Nonassociating Polar Liquids

6.1 INTRODUCTION

6.2 CHLOROBENZENE–METHANOL BINARY SYSTEM

6.3 CHLOROBENZENE–ETHANOL BINARY SYSTEM

6.4 CHLOROBENZENE–1-PROPANOL BINARY SYSTEM

6.5 CHLOROBENZENE–FORMAMIDE BINARY SYSTEM

6.6 CHLOROBENZENE–DIMETHYLFORMAMIDE BINARY SYSTEM

6.7 CHLOROBENZENE–N-METHYLFORMAMIDE BINARY SYSTEM

6.8 1,2-DICHLOROETHANE–METHANOL BINARY SYSTEM

6.9 1,2-DICHLOROETHANE–ETHANOL BINARY SYSTEM

6.10 1,2-DICHLOROETHANE–1-PROPANOL BINARY SYSTEM

6.11 DIMETHYLENE CHLORIDE–ETHANOL BINARY SYSTEM

6.12 2-NITROTOLUENE–DIMETHYLACETAMIDE BINARY SYSTEM

6.13 2-NITROTOLUENE–DIMETHYLSULFOXIDE BINARY SYSTEM

6.14 2-NITROTOLUENE–DIMETHYLFORMAMIDE BINARY SYSTEM

6.15 ETHANOL–NITROBENZENE BINARY SYSTEM

6.16 ETHANOL–NITROTOLUENE BINARY SYSTEM

6.17 2-NITROACETOPHENANE–ETHANOL BINARY SYSTEM

6.18 OTHER SIMILAR SYSTEMS20−22

6.19 CONCLUSION

References

7 - Structural Study of Binary Mixtures of Polar Liquids Containing Heterocyclic Compounds and Hydroxyl or Amino Groups

7.1 INTRODUCTION

7.2 PYRIDINE–METHANOL BINARY SYSTEM

7.3 PYRIDINE–ETHANOL BINARY SYSTEM

7.4 PYRIDINE–PROPANOL BINARY SYSTEM

7.5 PYRIDINE–BUTANOL BINARY SYSTEM

7.6 PYRIDINE–FORMAMIDE BINARY SYSTEM

7.7 PYRIDINE–N-METHYLFORMAMIDE BINARY SYSTEM

7.8 PYRIDINE–DIMETHYLFORMAMIDE BINARY SYSTEM

7.9 PYRIDINE–WATER BINARY SYSTEM

7.10 PYRIDINE–SULFOLANE BINARY SYSTEM

7.11 OTHER SIMILAR SYSTEMS

7.12 CONCLUSIONS

References

8 - Dielectric Relaxation and Molecular Dynamics in Associating Dipolar Liquids and Polyhydroxyl Polymers

8.1 INTRODUCTION

8.2 PROPYLENE GLYCOL–WATER

8.3 PROPYLENE GLYCOL–POLYPROPYLENE GLYCOL

8.4 POLYVINYLPYRROLIDONE–ETHYL ALCOHOL

8.5 POLYVINYLPYRROLIDONE–ETHYLENE GLYCOL

8.6 POLYVINYLPYRROLIDONE–POLYETHYLENE GLYCOL (400)

8.7 POLYVINYLPYRROLIDONE–GLYCEROL

8.8 OTHER SIMILAR SYSTEMS

8.9 CONCLUSION

References

9 - Structural Investigation of Biomolecules Through Dielectric Parameters

9.1 INTRODUCTION

9.2 WATER–SUCROSE BINARY SYSTEM

9.3 WATER–LACTOSE BINARY SYSTEM

9.4 WATER–MALTOSE BINARY SYSTEM

9.5 WATER–GLUCOSE BINARY SYSTEM

9.6 WATER–GLYCINE BINARY SYSTEM

9.7 WATER–ALANINE BINARY SYSTEM

9.8 WATER–PHENYLALANINE BINARY SYSTEM

9.9 WATER–TRYPTOPHAN BINARY SYSTEM

9.10 OTHER SIMILAR SYSTEM

9.11 CONCLUSION

References

10 - Permittivity Study of Bloods, Saliva, Tissue Cells, and Their Applications in Medical Instrumentations in the ...

10.1 INTRODUCTION

10.2 ANALYSIS OF SYSTEMS WITH CONDUCTIVITY IN TDR EXPERIMENT

10.3 PERMITTIVITY OF HUMAN BLOOD6

10.4 PERMITTIVITY OF SALIVA8

10.5 PERMITTIVITY OF TISSUE CELL

10.6 PORTABLE INSTRUMENTATION FOR DETECTION OF CANCER24

10.7 CONCLUSION

References

FURTHER READING

11 - Extraction of Significant Features From Permittivity Parameters of Binary Polar Liquids

11.1 INTRODUCTION

11.2 QUALITATIVE DESCRIPTION OF BINARY MIXTURES THROUGH EXCESS PROPERTIES AND MIXTURE MODELS

11.2.1 Classification From Excess Properties

11.2.1.1 Systems With (+,−) Behavior

11.2.1.2 Systems With (−, +) Behavior

11.2.1.3 Systems With (−,−) Behavior

11.2.1.4 Systems With (+, +) Behavior

11.2.1.5 Systems With (Hybrid (+−),−) Behavior

11.2.1.6 Systems With (Hybrid (− +), −) Behavior

11.2.1.7 Systems With (Hybrid (− +), +) Behavior

11.2.1.8 System With (+, Hybrid (−, +)) Behavior

11.2.1.9 Systems With (Hybrid (+−), Hybrid (+−)) Behavior

11.2.2 The Bruggeman Parameter, “a”

11.2.3 Classification From the Bruggeman Parameter, “a”

11.2.3.1 Systems With “a”﹥1

11.2.3.2 Systems With “a”<1

11.3 THE LUZAR MODEL

11.3.1 Theoretical Background

11.3.2 The Water–DMSO System

11.3.3 The Water–N,N-Methylformamide System

11.3.4 The Water–Dioxane System10,11

11.3.5 Other Similar Systems Studied by the Luzar Model

11.3.6 Quantum Chemical Computational Approach

11.4 CONCLUSION

References

Index

A

B

C

D

E

F

H

K

L

M

N

O

P

R

S

T

W

Z

Back Cover

The users who browse this book also browse