Silver sequestration of halides for the activation of Pd(OAc)2 catalyzed Mizoroki‐Heck reaction of 1,1 and 1,2 ‐ Disubstituted alkenes

Publisher: John Wiley & Sons Inc

E-ISSN: 1099-0739|32|3|aoc.4159-aoc.4159

ISSN: 0268-2605

Source: APPLIED ORGANOMETALLIC CHEMISTRY (ELECTRONIC), Vol.32, Iss.3, 2018-03, pp. : n/a-n/a

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Abstract

A ligand free catalytic system consisting of Pd(OAc)2 (cat) and stoichiometric quantities of silver salts, AgOAc or AgBF4, exhibit high efficiency in the Mizoroki‐Heck arylation, transforming aryl iodides and 1,1 as well as 1,2 disubstituted alkenes into 1,1,2 – trisubstituted aryl alkenes in excellent yields in very short reaction times.