Author: Badelin V.
Publisher: MAIK Nauka/Interperiodica
ISSN: 1070-3632
Source: Russian Journal of General Chemistry, Vol.83, Iss.5, 2013-05, pp. : 945-948
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Abstract
Protolytic dissociation constants of stepwise dissociation of glutamyl-glutamic and glycyl-glutamic acids in aqueous solutions at 298.15 K at ionic strengths of 0.1, 0.5, and 1.0 M on the NaCl background were measured by potentiometric titration. The thermodynamic dissociation constants were calculated. Using the obtained and published data, we discuss the effect of additional carboxy groups in the side chains of the molecule on the protolytic dissociation constants of peptides.
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