Dielectric study of the tilted columnar mesophase in three new chiral metallorganic discotic mesogens

Author: Palacios B.   Fuente M.R.D.L.   Angel M.   Jubindo P.   Iglesias R.   Luis J.   Sierra S.T.  

Publisher: Taylor & Francis Ltd

ISSN: 0267-8292

Source: Liquid Crystals, Vol.25, Iss.4, 1998-10, pp. : 481-485

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Abstract

Chiral oxovanadium(IV), copper(II) and palladium(II) beta-diketonates show a room temperature tilted columnar mesophase (rectangular P21). The dielectric response of these compounds was measured in the frequency range 10-2-109Hz. Three different relaxation processes have been observed in the columnar phase. One of them is only present in this mesophase and we suggest that it is a Goldstone-like mode, similar to the one present in the helical SmC* phases. In our case the presence of the helix was confirmed by circular dichroism studies.

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