Author： Matsuura Yukihito
Publisher： Taylor & Francis Ltd
ISSN： 1542-1406
Source： Molecular Crystals and Liquid Crystals, Vol.569, Iss.1, 2012-12, pp. : 103-111
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
I examined electrical conduction in polymeric μ-cyclopentadienylelement (Cp-E) complexes of the main group elements using the nonequilibrium Green's function formalism with the density functional theory. The polymeric Cp-E complexes of group 1 elements, which had ionic Cp-E bonds, showed very low conductance. In contrast, the polymeric Cp-E complexes of groups 13 and 14 elements exhibited enhanced n-type electrical conduction when a bias was applied between the electrodes, because the delocalized electronic states of the lowest unoccupied molecular orbital were within the bias window.
Related content
Molten potassium pyrosulphate: Reactions of oxides of ten main-group elements
Thermochimica Acta, Vol. 307, Iss. 2, 1997-12 ,pp. :
Access to resources
Recommend
Mechanisms of Oxygen Atom Transfer between Main‐Group Elements
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (ELECTRONIC), Vol. 2015, Iss. 24, 2015-08 ,pp. :
Temperature‐Dependent Electron Shuffle in Molecular Group 13/15 Intermetallic Complexes
ANGEWANDTE CHEMIE, Vol. 126, Iss. 43, 2014-10 ,pp. :