Dehydration/Rehydration Processes and the Porous Structure of a Tris(Macrocyclic) Carboxylate Copper(II) Complex

Author： Prikhod’ko A.  

Publisher： Springer Publishing Company

ISSN： 0040-5760

Source： Theoretical and Experimental Chemistry, Vol.41, Iss.3, 2005-05, pp. : 176-180

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

We have established that the crystal hydrate of the tris(macrocyclic) complex of copper with carboxylate, with a porous structure, undergoes stepwise dehydration leading to a change in its crystal lattice structure; but even total dehydration does not lead to loss of porosity in the latter. We have studied the sorption characteristics of the dehydrated sample with respect to water, methanol, and hexane.

Related content

Piezoquartz microweighing study of interaction of water, alcohol, and hydrocarbon vapors with a macrocyclic copper(II) carboxylate complex

By Tsymbal L.  

Theoretical and Experimental Chemistry, Vol. 41, Iss. 1, 2005-01 ,pp. : 58-63 (6)

Springer Publishing Company

Access to resources Recommend Favorite

A New Receptor of Aromatic Carboxylates Based on a Trismacrocyclic Complex of Copper(II) and Operating According to the Molecular Recognition Principle

By Comba P.  

Theoretical and Experimental Chemistry, Vol. 37, Iss. 4, 2001-07 ,pp. : 236-240 (5)

Springer Publishing Company

Access to resources Recommend Favorite

Synthesis, structure, and biological active evaluation of a new cyclic tetranuclear copper(II) complex bridged both by oxamido and carboxylate groups

By  

JOURNAL OF BIOCHEMICAL AND MOLECULAR TOXICOLOGY (FORMERLY JOURNAL OF BIOCHEMICAL TOXICOLOGY), Vol. 32, Iss. 1, 2018-01 ,pp. : n/a-n/a (NaN)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Synthesis and characterization of copper(II) tetraaza macrocyclic complex with 2- benzimidazolepropionate ligand

By Choi Ki-Young  

Journal of Chemical Crystallography, Vol. 34, Iss. 9, 2004-09 ,pp. : 603-607 (5)

Springer Publishing Company

Access to resources Recommend Favorite

Synthesis and characterization of carboxylate-bridged copper(II) dinuclear complex

By Choi Ki-Young   Park Sun-Young   Shin Ae-Kyung  

Journal of Chemical Crystallography, Vol. 36, Iss. 1, 2006-01 ,pp. : 7-12 (6)

Springer Publishing Company

Access to resources Recommend Favorite