From mono- to poly-nuclear heteroleptic alkaline earth-titanium complexes containing 2,2,6,6-tetramethylheptane-3,5-dionate (thd) and pyrazole (Hpz) or 3,5-dimethylpyrazole (Hpz*) ligands. - Synthesis, spectroscopic and structural characterization of [Ba(thd) 2 (Hpz) 2 ] 2 , [Sr(thd) 2 (Hpz*) 3 ], [Ba(thd) 2 (Hpz*) 2 ] 2 and the heterometallic {[Ti(thd) 2 ( 3 -O)( -Bu t C(O)CH 2 CH 2 O)Sr(thd)( -Bu t COO)] 2 Sr(Hpz) 2 }

Author: Pettinari C.   Marchetti F.   Pettinari R.   Vertlib V.   Drozdov A.   Timokhin I.   Troyanov S.   Min Y.-S.   Kim D.  

Publisher: Elsevier

ISSN: 0020-1693

Source: Inorganica Chimica Acta, Vol.355, Iss.unknown, 2003-11, pp. : 157-167

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Abstract