Kinetics and mechanisms of homogeneous catalytic reactions. Part 5. Regioselective reduction of heteroaromatic nitrogen compounds catalysed by [OsH(CO)(NCMe) 2 (PPh 3 ) 2 ]BF 4

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Transition Metal Chemistry, Vol. 29, Iss. 2, 2004-03 ,pp. : 221-228

Springer Publishing Company

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The structure of [Co 3 ( 5 -C 5 H 5 ) 3 ( 3 -S)( 3 -CSMe)] + , and the reactions of the metal cluster cations [{Co( 5 -C 5 H 5 )} 2 {Fe(CO) 2 (PPh 3 )}( 3 -S)( 3 -CSR)] + and [{Co( 5 -C 5 H 5 )} 3 ( 3 -S)( 3 -CSR)] + (R=Me, Et) with nucleophiles

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Synthesis and characterization of the cluster complexes containing tetrahedral FeCrCo( 3 -S) cluster cores generated by isolobal displacement reactions. Crystal structures of ( 5 -RC 5 H 4 )FeCrCo( 3 -S)(CO) 8 (R=H, CO 2 Et) and FeCo 2 ( 3 -S) 2 (CO) 9

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Transition metal-substituted paraffins: synthesis and properties of some -saturated heterobimetallic complexes containing Mo and W or Fe and the crystal structures of [( 5 -C 5 H 5 )(CO) 3 W(CH 2 ) 3 Mo(CO) 2 (PPh 3 )( 5 -C 5 H 5 )] and [( 5 -C 5 H 5 )(CO) 2 (PPh 3 )Mo(CH 2 ) 3 Fe(CO) 2 ( 5 -C 5 H 5 )]

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Four isomers from the oxidative addition of Me 3 SnH to Os(CO) 2 (PPh 3 ) 3 and the crystal structure of Os(SnMeI 2 )I(CO) 2 (PPh 3 ) 2 , in which the pairs of CO and PPh 3 ligands are mutually trans

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