Effect of transition metal ions on photocatalytic activity of ZnO in bleaching of some dyes

Author: Bhandari Suruchi   Vardia Jitendra   Malkani R. K.   Ameta Suresh C.  

Publisher: Taylor & Francis Ltd

ISSN: 0277-2248

Source: Toxicological and Environmental Chemistry, Vol.88, Iss.1, 2006-01, pp. : 35-44

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

The photocatalytic bleaching of some dyes (erythrosin-B, fast green FCF and eosin Y) was carried in the presence of semiconducting zinc oxide and was observed spectrophotometrically. The effects of various operating variables like pH, concentration of dyes, amount of semiconductor and light intensity on the efficiency of the reaction were also observed. Attempts have been made to study the effect of the addition of other metal ions (Fe 2+ , Ni 2+ , Ag + , Cu 2+ , Co 2+ , V 2+ and Mn 2+ ). All the added metal ions increase the reaction rate to some extent. It was also observed that Fe 2+ is most effective in photobleaching of erythrosin-B, whereas V 2+ is more effective in the cases of fast green FCF and eosin Y. A tentative mechanism has been proposed.