Ethylene Methacrylate (EMA) Co-polymer Toughened Polymethyl Methacrylate Blends: Physico-mechanical, Optical, Thermal and Chemical Properties

Author： Poomalai P. Varghese T. O.

Publisher： Taylor & Francis Ltd

ISSN： 0360-2559

Source： Polymer-Plastics Technology and Engineering, Vol.48, Iss.9, 2009-09, pp. : 958-965

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Abstract

Polymethyl methacrylate (PMMA) was blended with ethylene methacrylate (EMA) copolymer in different compositions by melt mixing technique using Haake Rheochord twin screw extruder. The physico-mechanical, thermal, optical and chemical properties of PMMA/EMA blends were investigated with special reference to the blend compositions. The impact strength of the blends was found to increase significantly with increase in EMA content, without affecting the optical properties significantly. Optical micrograph images of the blends reveals that the rubbery phase dispersed as domains in the continuous PMMA matrix at 5 and 10 wt. % addition of EMA. The PMMA/EMA, 80/20 blend was found to exist as co-continuous system. Attempts have been made to correlate changes in morphology with mechanical properties. The influence of chemical ageing and heat ageing on the mechanical performance of PMMA/EMA blends has been studied. Four composite models such as series model, parallel model, Hapin-Tsai and Kerner's model have been used to fit the experimental tensile strength, tensile modulus and surface hardness.