Brønsted Acidic Ionic Liquid: An Efficient and Reusable Catalyst for the Synthesis of 3,4‐Dihydropyrimidin‐2(1 H )‐ones

Author: Zheng Renwei   Wang Xiaoxia   Xu Hui   Du Jingxing  

Publisher: Taylor & Francis Ltd

ISSN: 0039-7911

Source: Synthetic Communications, Vol.36, Iss.11, 2006-06, pp. : 1503-1513

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Abstract

A novel ionic liquid, 3-carboxymethyl-1-methylimidazolium bisulfate (CMImHSO 4 ), was synthesized and used as a recyclable catalyst for the Biginelli reaction under solvent-free conditions. High yields of various substituted 3,4-dihydropyrimidin-2(1 H )-ones (or thiones) were obtained. The ionic liquid can be recovered and recycled easily without loss of activity.

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