Author： Srivastava Rajiv Zych Andrew Jenkins David Wang Hong-Jun Chen Zhen-Jia Fairfax David
Publisher： Taylor & Francis Ltd
ISSN： 0039-7911
Source： Synthetic Communications, Vol.37, Iss.3, 2007-01, pp. : 431-438
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Abstract
A variety of aryl nitriles were prepared in excellent yield from the palladium(II) acetate-catalyzed cross-coupling of aryl triflates and zinc cyanide under microwave irradiation conditions. To facilitate purification, polymer-supported triphenylphosphine was used as the palladium ligand. Comparison to the corresponding thermal conditions revealed much shorter reaction times with comparable yields.
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